Oxidation of Benzene Catalyzed by 2,2'-Bipyridine and 1,10-Phenantroline Cu(II) Complexes

被引：18
作者：
Detoni, Chaline [1 ,2 ]
Carvalho, Nakedia M. F. [1 ]
de Souza, Rodrigo O. M. A. [1 ]
Aranda, Donato A. G. [2 ]
Antunes, O. A. C. [1 ]
机构：
[1] Univ Fed Rio de Janeiro, Inst Quim, BR-21945970 Rio De Janeiro, Brazil
[2] Univ Fed Rio de Janeiro, Escola Quim, BR-21941909 Rio De Janeiro, Brazil
来源：
CATALYSIS LETTERS | 2009年 / 129卷 / 1-2期
关键词：
Selective benzene oxidation; Mononuclear Cu(II) complexes; 2,2 '-Bipyridine; 1,10-Phenantroline; Peroxides; Biomimetic catalyst; CYCLOHEXANE; PHENOL; LIMONENE; CRYSTAL;
D O I：
10.1007/s10562-008-9830-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The use of mononuclear Cu(II) 2,2'-bipyridine and 1,10-phenantroline complexes as catalysts in the oxidation of benzene, using hydrogen peroxide and tert-butyl hydroperoxide as oxidant in CH3CN/H2O solution is presented. The reactions were carried out at 25 and at 50 A degrees C. The complexes [Cu(bipy)(3)]Cl-2 center dot A 6H(2)O (1), [Cu(bipy)(2)Cl]Cl center dot A 5H(2)O (2), [Cu(bipy)Cl-2] (3), [Cu(phen)(3)]Cl-2 center dot A 7H(2)O (4), [Cu(phen)(2)Cl]Cl center dot A 5H(2)O (5), [Cu(phen)Cl-2] (6) were able to oxidize benzene into phenol, hydroquinone and p-benzoquinone. Highest conversion (22%) was obtained using [Cu(Phen)Cl-2] (6) as catalyst.
引用
收藏
页码：79 / 84
页数：6
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