SYNTHESIS OF INDOLINES VIA A PHOTOCATALYTIC INTRAMOLECULAR REDUCTIVE CYCLIZATION REACTION

被引：1
作者：
Yamaguchi, Eiji [1 ]
Goto, Yumiko [1 ]
Itoh, Akichika [1 ]
机构：
[1] Gifu Pharmaceut Univ, Lab Pharmaceut Synthet Chem, 1-25-4 Daigaku Nishi, Gifu 5011196, Japan
来源：
HETEROCYCLES | 2020年 / 101卷 / 01期
关键词：
CATALYZED ASYMMETRIC HYDROGENATION; AMINATION; TRANSFORMATIONS; C(SP(3))-H; ACCESS; BONDS;
D O I：
10.3987/COM-19-S(F)8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Herein, we synthesized a series of indolines using a photocatalytic intramolecular reductive cyclization reaction. This reaction uses several N-allyl-2-iodoanilines in the presence of 10-phenylphenothiazine (Ph-PTZ) as an organic photocatalyst. Further, the corresponding aryl radical is generated through the reductive cleavage of the C I bond, generating 5-exo cyclization products.
引用
收藏
页码：177 / 185
页数：9
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