Total synthesis of naturally configured pyrrhoxanthin, a carotenoid butenolide from plankton

被引：26
作者：
Burghart, Jochen [1 ]
Brueckner, Reinhard [1 ]
机构：
[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 40期
关键词：
bifunctional building blocks; cross-coupling; dyes/pigments; natural products; total syntheses;
D O I：
10.1002/anie.200801638
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A carotenoid from the chemical kitchen: Two sequential Stille couplings of an unsymmetric distannane building block with a bromoolefin and a bromoalkyne terminated a highly convergent synthesis of the title compound, pyrrhoxanthin (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：7664 / 7668
页数：5
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