Total synthesis of naturally configured pyrrhoxanthin, a carotenoid butenolide from plankton

被引：26

作者：

Burghart, Jochen ^{[1
]}

Brueckner, Reinhard ^{[1
]}

机构：

[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 40期

关键词：

bifunctional building blocks; cross-coupling; dyes/pigments; natural products; total syntheses;

D O I：

10.1002/anie.200801638

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A carotenoid from the chemical kitchen: Two sequential Stille couplings of an unsymmetric distannane building block with a bromoolefin and a bromoalkyne terminated a highly convergent synthesis of the title compound, pyrrhoxanthin (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7664 / 7668

页数：5

共 76 条

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