Rational Design and Synthesis of Cyano-Bridged Coordination Polymers with Precise Control of Particle Size from 20 to 500 nm

被引：35

作者：

Chiang, Ya-Dong ^{[1
]}

Hu, Ming ^{[2
]}

Kamachi, Yuichiro ^{[2
]}

Ishihara, Shinsuke ^{[2
]}

Takai, Kimiko ^{[2
]}

Tsujimoto, Yoshihiro ^{[2
]}

Ariga, Katsuhiko ^{[2
]}

Wu, Kevin C-W. ^{[1
]}

Yamauchi, Yusuke ^{[2
,3
,4
]}

机构：

[1] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan

[2] Natl Inst Mat Sci, World Premier Int WPI Res Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan

[3] Japan Sci & Technol Agcy JST, PRESTO, Kawaguchi, Saitama 3320012, Japan

[4] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 18期

关键词：

Coordination polymers; Nanoparticles; Chelates; Dyes; Pigments; Controlled crystallization; PRUSSIAN BLUE NANOPARTICLES; METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; CRYSTALLIZATION; ADSORPTION; ANALOGS; SPIN; MN; NI;

D O I：

10.1002/ejic.201300112

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We demonstrate that the particle sizes in cyano-bridged coordination polymers consisting of NiII-CN-FeII units are precisely controlled by changing the amount of chelating agent, sodium citrate. With an increase in the amount of chelating agent added, the average size of the particles gradually increases from 20 to 350 nm with retention of a well-defined cubic shape. Furthermore, the use of different Fe sources expands the possible control range up to 500 nm.

引用

页码：3141 / 3145

页数：5

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