Self-assembled biomimetic nanoreactors II: Noble metal active centers

被引：4
|
作者：
McTaggart, Matt [1 ]
Malardier-Jugroot, Cecile [1 ]
Jugroot, Manish [2 ]
机构：
[1] Royal Mil Coll Canada, Dept Chem & Chem Engn, Kingston, ON K7K 7B4, Canada
[2] Royal Mil Coll Canada, Dept Mech & Aerosp Engn, Kingston, ON K7K 7B4, Canada
来源：
CHEMICAL PHYSICS LETTERS | 2015年 / 636卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
GOLD NANOPARTICLES; PLATINUM NANOPARTICLES; CATALYTIC-ACTIVITY; ETHANOL; HYDROGENATION; SURFACES; ATOMS; CORE; SIZE;
D O I：
10.1016/j.cplett.2015.08.015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The structure and stability of polymer-metal nanoreactors is detailed, including a complete characterization of the first successful synthesis of stable, dispersible, atomically thin gold nanosheets. Further developments in the synthesis of monodisperse, similar to 2.5 nm platinum nanoclusters in aqueous solution and ambient conditions are described and pH stability of the composite material is established. The facile nanoreactor synthesis, environmentally friendly reaction conditions, and structural stability makes these biomimetic systems attractive for applications ranging from chemical detoxification to nanoelectronics. Crown Copyright (C) 2015 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：221 / 227
页数：7
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