DyMnO3/Fe2O3 nanocomposites: simple sol-gel auto-combustion technique and photocatalytic performance for water treatment

被引:21
作者
Baladi, Mahin [1 ]
Ghanbari, Mojgan [1 ]
Valian, Movlud [1 ]
Salavati-Niasari, Masoud [1 ]
机构
[1] Univ Kashan, Inst Nano Sci & Nano Technol, POB 87317-51167, Kashan, Iran
基金
美国国家科学基金会;
关键词
DyMnO3; Fe2O3; Green synthesis; Nanocomposite; Photocatalyst; Water purification; Sol-gel; HYDROTHERMAL SYNTHESIS; ELECTRICAL-PROPERTIES; PARTICLES; PHOTODEGRADATION; NANOPARTICLES;
D O I
10.1007/s11356-020-11324-8
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Recently, nanocomposite photocatalysts based on semiconductors have drawn consideration due to their suitable bandgap. Combination of tow of several semiconductors can slow down the electron-hole recombination. For this purpose, we have introduced DyMnO3/Fe2O3 nanocomposite as a novel and efficient catalyst for water purification. For this regard, DyMnO3/Fe2O3 nanocomposite has been fabricated by a simple and green sol-gel auto-combustion technique. The impact of calcination temperature, time, and types of fuel was investigated on morphology, structure, and purity of the products. The samples were identified by XRD, FTIR, FESEM, HRTEM, BET, and DRS. The bandgap was calculated by DRS to be 3.20 and 3.28 eV for Fe2O3 and DyMnO3. Due to the appropriate bandgap, DyMnO3/Fe2O3 degraded 80% of methylene blue under UV light. The future aspects of the DyMnO3/Fe2O3 application can be applied in thermoelectric materials, solid fuel cells, electrochemical gas sensors, and electrochemical biosensors.
引用
收藏
页码:11066 / 11076
页数:11
相关论文
共 36 条
[1]   Photo-degradation of methylene blue: photocatalyst and magnetic investigation of Fe2O3-TiO2 nanoparticles and nanocomposites [J].
Abbasi, Ali ;
Ghanbari, Davood ;
Salavati-Niasari, Masoud ;
Hamadanian, Masood .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2016, 27 (05) :4800-4809
[2]   Investigation of multiferroic behaviour of TbMnO3 nanoplates [J].
Acharya, S. A. ;
Khule, S. M. ;
Gaikwad, V. M. .
MATERIALS RESEARCH BULLETIN, 2015, 67 :111-117
[3]   A guanylurea-functionalized conjugated polymer enables RNA interference in ex vivo human airway epithelium [J].
Ahmed, Md Salauddin ;
Dutta, Rajib Kumar ;
Manandhar, Prakash ;
Li, Xuerong ;
Torabi, Hooman ;
Barrios, Alfonso ;
Wang, Ping ;
Chinnapaiyan, Srinivasan ;
Unwalla, Hoshang Jehangir ;
Moon, Joong Ho .
CHEMICAL COMMUNICATIONS, 2019, 55 (54) :7804-7807
[4]   Synthesis of iron and copper cluster-grafted zinc oxide nanorod with enhanced visible-light-induced photocatalytic activity [J].
Alam, Umair ;
Khan, Azam ;
Bahnemann, Detlef ;
Muneer, M. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2018, 509 :68-72
[5]   Hierarchically SrTiO3@TiO2@Fe2O3 nanorod heterostructures for enhanced photoelectrochemical water splitting [J].
Bashiri, Robabeh ;
Irfan, Muhammad Syahmi ;
Mohamed, Norani Muti ;
Sufian, Suriati ;
Ling, Liew Yi ;
Suhaimi, Nur Amirah ;
Samsudin, Mohamad Fakhrul Ridhwan .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (48) :24607-24619
[6]   Depth-dependent spin dynamics in TbMnO3 thin films measured by low energy muon spin relaxation Depth-dependent spin dynamics in TbMnO3 thin films measured by low energy muon spin relaxation [J].
Bator, Matthias ;
Hu, Yi ;
Luetkens, Hubertus ;
Niedermayer, Christof ;
Prokscha, Thomas ;
Suter, Andreas ;
Salman, Zaher ;
Kenzelmann, Michel ;
Schneider, Christof W. ;
Lippert, Thomas .
12TH INTERNATIONAL CONFERENCE ON MUON SPIN ROTATION, RELAXATION AND RESONANCE (MUSR2011), 2012, 30 :137-141
[7]   Size-dependent structure and magnetic properties of DyMnO3 nanoparticles [J].
Cai, Xuan ;
Shi, Lei ;
Zhou, Shiming ;
Zhao, Jiyin ;
Guo, Yuqiao ;
Wang, Cailin .
JOURNAL OF APPLIED PHYSICS, 2014, 116 (10)
[8]   New synthesis routes for obtaining dysprosium manganese perovskites [J].
Carp, O ;
Patron, L ;
Ianculescu, A ;
Pasuk, J ;
Olar, R .
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 351 (1-2) :314-318
[9]   Effects of substituting Mn with Ga in the multiferroic properties of TbMnO3 [J].
Cuartero, V. ;
Blasco, J. ;
Garcia, J. ;
Subias, G. ;
Sanchez, M. C. .
INTERNATIONAL CONFERENCE ON MAGNETISM (ICM 2009), 2010, 200
[10]   Microstructure-dependent dielectric properties of TbMnO3 in Au/TbMnO3/YBa2Cu3O7-x capacitors [J].
Cui, Yimin ;
Cai, Wei ;
Li, Yuan ;
Qian, Jiang Qian ;
Xu, Ping ;
Wang, Rongming ;
Yao, Junen ;
Zhang, Liuwan .
JOURNAL OF APPLIED PHYSICS, 2006, 100 (03)