Perovskite-type Oxide LaMnO3: An Efficient and Recyclable Heterogeneous Catalyst for the Wet Aerobic Oxidation of Lignin to Aromatic Aldehydes

被引:102
作者
Deng, Haibo [1 ]
Lin, Lu [1 ]
Sun, Yong [1 ]
Pang, Chunsheng [1 ]
Zhuang, Junping [1 ]
Ouyang, Pingkai [2 ]
Li, Zhenjiang [2 ]
Liu, Shijie
机构
[1] S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China
[2] Nanjing Univ Technol, Coll Med & Life Sci, Nanjing 210009, Jiangsu Prov, Peoples R China
关键词
Perovskite-type oxide LaMnO3; Catalytic wet aerobic oxidation; Lignin; Aromatic aldehydes; Activity; Reusability;
D O I
10.1007/s10562-008-9588-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The perovskite-type oxide catalyst LaMnO3 prepared by the sol-gel method was found to be an efficient heterogeneous and recyclable catalyst for the wet aerobic oxidation of lignin to aromatic aldehydes. The lignin conversion rate and the yield of each aromatic aldehyde were enhanced significantly by the catalytic process as compared with the non-catalyzed process. Moreover, the activity, specific surface area and perovskite-type structure of the LaMnO3 catalyst remained nearly unchanged after five successive recycles of catalytic reactions.
引用
收藏
页码:106 / 111
页数:6
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