Primary and tertiary amines bifunctional graphene oxide for cooperative catalysis

被引：95
作者：
Zhang, Wenfeng [1 ]
Wang, Shanshan [1 ]
Ji, Junyi [1 ]
Li, Yang [1 ]
Zhang, Guoliang [1 ]
Zhang, Fengbao [1 ]
Fan, Xiaobin [1 ]
机构：
[1] Tianjin Univ, State Key Lab Chem Engn, Key Lab Green Chem Technol, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
来源：
NANOSCALE | 2013年 / 5卷 / 13期
基金：
中国国家自然科学基金;
关键词：
OXYGEN REDUCTION REACTION; FUNCTIONALIZED GRAPHENE; RECYCLABLE CATALYST; FACILE SYNTHESIS; GRAPHITE OXIDE; NANOPARTICLES; OXIDATION; PD; CYCLOHEXENE; HYBRIDS;
D O I：
10.1039/c3nr01323e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this study, primary and tertiary amine bifunctional graphene oxide (GO-NH2-NEt2) was prepared by silylanization of graphene oxide (GO) with amine-terminal silanes. The obtained GO-NH2-NEt2 was characterized by infrared spectrum (FTIR), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS). Systematic studies demonstrated the GO-NH2-NEt2 had excellent catalytic activities and 100% selectivity in the classic trans-beta-nitrostyrene forming reaction.
引用
收藏
页码：6030 / 6033
页数：4
相关论文
共 35 条
  • [1] Honeycomb Carbon: A Review of Graphene
    Allen, Matthew J.
    Tung, Vincent C.
    Kaner, Richard B.
    [J]. CHEMICAL REVIEWS, 2010, 110 (01) : 132 - 145
  • [2] Acid-base bifunctional and dielectric outer-sphere effects in heterogeneous catalysis: A comparative investigation of model primary amine catalysts
    Bass, JD
    Solovyov, A
    Pascall, AJ
    Katz, A
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (11) : 3737 - 3747
  • [3] Graphene supported Au-Pd bimetallic nanoparticles with core-shell structures and superior peroxidase-like activities
    Chen, Hongyu
    Li, Yang
    Zhang, Fengbao
    Zhang, Guoliang
    Fan, Xiaobin
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (44) : 17658 - 17661
  • [4] Synthesis of "Clean" and Well-Dispersive Pd Nanoparticles with Excellent Electrocatalytic Property on Graphene Oxide
    Chen, Xiaomei
    Wu, Genghuang
    Chen, Jinmei
    Chen, Xi
    Xie, Zhaoxiong
    Wang, Xiaoru
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (11) : 3693 - 3695
  • [5] Bioinspired Layered Composites Based on Flattened Double-Walled Carbon Nanotubes
    Cheng, Qunfeng
    Li, Mingzhu
    Jiang, Lei
    Tang, Zhiyong
    [J]. ADVANCED MATERIALS, 2012, 24 (14) : 1838 - 1843
  • [6] Liquid-phase exfoliation, functionalization and applications of graphene
    Cui, Xu
    Zhang, Chenzhen
    Hao, Rui
    Hou, Yanglong
    [J]. NANOSCALE, 2011, 3 (05) : 2118 - 2126
  • [7] Preparation and characterization of graphene oxide paper
    Dikin, Dmitriy A.
    Stankovich, Sasha
    Zimney, Eric J.
    Piner, Richard D.
    Dommett, Geoffrey H. B.
    Evmenenko, Guennadi
    Nguyen, SonBinh T.
    Ruoff, Rodney S.
    [J]. NATURE, 2007, 448 (7152) : 457 - 460
  • [8] Noble metal (Pd, Ru, Rh, Pt, Au, Ag) doped graphene hybrids for electrocatalysis
    Giovanni, Marcella
    Poh, Hwee Ling
    Ambrosi, Adriano
    Zhao, Guanjia
    Sofer, Zdenek
    Sanek, Filip
    Khezri, Bahareh
    Webster, Richard D.
    Pumera, Martin
    [J]. NANOSCALE, 2012, 4 (16) : 5002 - 5008
  • [9] Electronic transport properties of individual chemically reduced graphene oxide sheets
    Gomez-Navarro, Cristina
    Weitz, R. Thomas
    Bittner, Alexander M.
    Scolari, Matteo
    Mews, Alf
    Burghard, Marko
    Kern, Klaus
    [J]. NANO LETTERS, 2007, 7 (11) : 3499 - 3503
  • [10] FePt Nanoparticles Assembled on Graphene as Enhanced Catalyst for Oxygen Reduction Reaction
    Guo, Shaojun
    Sun, Shouheng
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (05) : 2492 - 2495
1234