Removal of mercury from aqueous solutions using activated carbon prepared from agricultural by-product/waste

被引:166
作者
Rao, M. Madhava [1 ]
Reddy, D. H. K. Kumar [1 ]
Venkateswarlu, Padala [1 ]
Seshaiah, K. [1 ]
机构
[1] Sri Venkateswara Univ, Dept Chem, Analyt & Environm Chem Div, Tirupati 517502, Andhra Pradesh, India
关键词
Mercury; Removal; Ceiba pentandra hulls; Phaseolus aureus hulls; Cicer arietinum waste; SURFACE FUNCTIONAL-GROUPS; WASTE-WATER; CHEMICAL-PROPERTIES; SEWAGE-SLUDGE; BAGASSE PITH; ADSORPTION; CADMIUM; EQUILIBRIUM; KINETICS; SORPTION;
D O I
10.1016/j.jenvman.2007.12.019
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Removal of mercury from aqueous Solutions using activated carbon prepared from Ceiba pentandra hulls, Phaseolus aureus hulls and Cicer arietinum waste was investigated. The influence of various parameters such as effect of pH, contact time, initial metal ion concentration and adsorbent dose for the removal of mercury was Studied using a batch process. The experiments demonstrated that the adsorption process corresponds to the pseudo-second-order-kinetic models and the equilibrium adsorption data fit the Freundlich isotherm model well. The prepared adsorbents ACCPH, ACPAH and ACCAW had removal capacities of 25.88 mg/g, 23.66 mg/g and 22.88 mg/g, respectively, at an initial Hg(II) concentration of 40 mg/L. The order of Hg(II) removal capacities of these three adsorbents was ACCPH > ACPAH > ACCAW. The adsorption behavior of the activated carbon is explained on the basis of its chemical nature. The feasibility of regeneration of spent activated carbon adsorbents for recovery of Hg(II) and reuse of the adsorbent was determined using HCl solution. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:634 / 643
页数:10
相关论文
共 27 条
[1]  
Baeyens R., 1996, GLOBAL REGIONAL MERC
[2]   Decolorization of molasses' wastewater using activated carbon prepared from cane bagasse [J].
Bernardo, EC ;
Egashira, R ;
Kawasaki, J .
CARBON, 1997, 35 (09) :1217-1221
[3]   Physical and chemical properties study of the activated carbon made from sewage sludge [J].
Chen, XG ;
Jeyaseelan, S ;
Graham, N .
WASTE MANAGEMENT, 2002, 22 (07) :755-760
[4]   Adsorption of metal ions on nitrogen surface functional groups in activated carbons [J].
Jia, YF ;
Xiao, B ;
Thomas, KM .
LANGMUIR, 2002, 18 (02) :470-478
[5]   Adsorption of cadmium ions on oxygen surface sites in activated carbon [J].
Jia, YF ;
Thomas, KM .
LANGMUIR, 2000, 16 (03) :1114-1122
[6]   Mercury(II) adsorption by activated carbon made from sago waste [J].
Kadirvelu, K ;
Kavipriya, M ;
Karthika, C ;
Vennilamani, N ;
Pattabhi, S .
CARBON, 2004, 42 (04) :745-752
[7]  
Kannan N, 2005, INDIAN J CHEM TECHN, V12, P522
[8]  
Krishnan KA, 2003, WATER SA, V29, P147
[9]  
Krishnan KA, 2002, J HAZARD MATER, V92, P161, DOI 10.1016/S0304-3894(02)00014-6
[10]   Importance of activated carbon's oxygen surface functional groups on elemental mercury adsorption [J].
Li, YH ;
Lee, CW ;
Gullett, BK .
FUEL, 2003, 82 (04) :451-457