Direct electron transfer based enzymatic fuel cells

被引：207

作者：

Falk, Magnus ^{[1
]}

Blum, Zoltan ^{[1
]}

Shleev, Sergey ^{[1
]}

机构：

[1] Malmo Univ, Fac Hlth & Soc, S-20506 Malmo, Sweden

来源：

ELECTROCHIMICA ACTA | 2012年 / 82卷

基金：

瑞典研究理事会;

关键词：

Enzymatic fuel cells; Direct electron transfer; Implantable biodevices; Ex vivo situations; Smart electronic contact lenses; GLUCOSE/OXYGEN BIOFUEL CELL; CARBON NANOTUBES; CYTOCHROME-C; DIRECT BIOELECTROCATALYSIS; BILIRUBIN OXIDASE; GRAPHITE-ELECTRODES; MULTICOPPER OXIDASES; GOLD NANOPARTICLE; CRYSTAL-STRUCTURE; CELLOBIOSE DEHYDROGENASE;

D O I：

10.1016/j.electacta.2011.12.133

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In this mini-review we briefly describe some historical developments made in the field of enzymatic fuel cells (FCs), discussing important design considerations taken when constructing mediator-, cofactor-, and membrane-less biological FCs (BFCs). Since the topic is rather extensive, only BFCs utilizing direct electron transfer (DET) reactions on both the anodic and cathodic sides are considered. Moreover, the performance of mostly glucose/oxygen biodevices is analyzed and compared. We also present some unpublished results on mediator-, cofactor-, and membrane-less glucose/oxygen BFCs recently designed in our group and tested in different human physiological fluids, such as blood, plasma, saliva, and tears. Finally, further perspectives for BFC applications are highlighted. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：191 / 202

页数：12

共 111 条

[1] Development of alcohol/O2 biofuel cells using salt-extracted tetrabutylammonium bromide/Nafion membranes to immobilize dehydrogenase enzymes [J].