Synthesis of rotacatenanes by the combination of Cu-mediated threading reaction and the template method: the dual role of one ligand

被引：33

作者：

Hayashi, Ryuto ^{[1
]}

Wakatsuki, Kota ^{[1
]}

Yamasaki, Ryu ^{[1
]}

Mutoh, Yuichiro ^{[1
]}

Kasama, Takeshi ^{[2
]}

Saito, Shinichi ^{[1
]}

机构：

[1] Tokyo Univ Sci, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan

[2] Tokyo Med & Dent Univ, Res Ctr Med & Dent Sci, Bunkyo Ku, Tokyo 1138510, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 02期

关键词：

DIRECTED SYNTHESIS; RING SIZE; MOLECULAR SHUTTLES; BLOCKING GROUP; ROTAXANES; CATENANES; MACROCYCLE; STABILITY; ION;

D O I：

10.1039/c3cc47425a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rotacatenanes were synthesized by the catalytic reaction using a macrocyclic phenanthroline-CuI complex followed by the installation of another ring by the template method. In this approach, the size of the ring component of the rotaxane turns out to be a very important factor for the synthesis of rotacatenanes.

引用

页码：204 / 206

页数：3

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