Two-dimensional (2D) Ti3C2Tx MXene nanosheets with superior adsorption behavior for phosphate and nitrate ions from the aqueous environment

被引:93
作者
Karthikeyan, Perumal [1 ,2 ]
Elanchezhiyan, S. SD. [2 ]
Preethi, Jayaram [2 ]
Talukdar, Kristy [2 ]
Meenakshi, Sankaran [1 ]
Park, Chang Min [2 ]
机构
[1] Deemed Univ, Dept Chem, Gandhigram Rural Inst, Dindigul 624302, Tamil Nadu, India
[2] Kyungpook Natl Univ, Dept Environm Engn, 80 Daehak Ro, Daeg 41566, South Korea
基金
新加坡国家研究基金会;
关键词
MXenes; Adsorption; Kinetics; Isotherm; Toxic anions; SIMULTANEOUS REMOVAL; ACTIVATED CARBON; COMPOSITE; CHITOSAN;
D O I
10.1016/j.ceramint.2020.08.183
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
With the advancement of modern industries and metropolitan areas, negative environmental impacts such as eutrophication have become serious issues obstructing the usage of water sources in many countries. In this study, two-dimensional (2D) MXene materials were employed for the adsorptive removal of phosphate and ni-trate ions from waters. The adsorption parameters of the sorption system including reaction time, solution pH, background ions, and reusability, were evaluated in batch experiments. Material characterization techniques, including X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, energy-dispersive X-ray analysis, Fourier transform infrared spectroscopy, thermal gravimetric analysis, Brunauer-Emmett-Teller analysis, and high-resolution transmission electron microscopy were performed. The mechanism of removing phosphate and nitrate was clearly described by various kinds of interactions such as electrostatic interactions, and the complexation was significant to elucidate the adsorption mechanism. The adsorption data for phosphate and nitrate update was determined using different isotherms and kinetic models. Reusability and field studies on the MXenes were also conducted. The above findings demonstrate that 2D MXenes could act as promising adsorbents for the elimination of toxic ions from water/wastewater.
引用
收藏
页码:732 / 739
页数:8
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