Ultrathin Nanosheets of Vanadium Diselenide: A Metallic Two-Dimensional Material with Ferromagnetic Charge-Density-Wave Behavior

被引：257

作者：

Xu, Kun ^{[1
,2
]}

Chen, Pengzuo ^{[1
,2
]}

Li, Xiuling ^{[3
,4
]}

Wu, Changzheng ^{[1
,2
]}

Guo, Yuqiao ^{[1
,2
]}

Zhao, Jiyin ^{[1
,2
]}

Wu, Xiaojun ^{[1
,2
,3
,4
]}

Xie, Yi ^{[1
,2
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China

[3] Univ Sci & Technol China, CAS Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China

[4] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 40期

基金：

中国国家自然科学基金;

关键词：

charge density waves; metallic behavior; room temperature ferromagnetism; ultrathin nanosheets; vanadium selenide; MOS2;

D O I：

10.1002/anie.201304337

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new metallic 2D material with high electrical conductivity (1×103 S m-1) consists of VSe2 ultrathin nanosheets with 4-8 Se-V-Se atomic layers. This is the first 2D transition-metal dichalcogenide with intrinsic room-temperature ferromagnetism. The nanosheets increase the charge-density-wave transition temperature to 135 K by dimensional reduction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10477 / 10481

页数：5

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