Comparatively high yield methanol production from gas phase partial oxidation of methane

被引：57

作者：

Zhang, QJ ^{[1
]}

He, DH ^{[1
]}

Li, JL ^{[1
]}

Xu, BQ ^{[1
]}

Liang, Y ^{[1
]}

Zhu, QM ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Chem, State Key Lab C1 Chem & Technol, Beijing 100084, Peoples R China

来源：

APPLIED CATALYSIS A-GENERAL | 2002年 / 224卷 / 1-2期

关键词：

gas phase; partial oxidation; methane; methanol;

D O I：

10.1016/S0926-860X(01)00820-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gas phase partial oxidation of methane to methanol has been carried out in a specially designed reactor. A comparatively high yield of methanol (ca. 7-8%, methanol selectivity of 60% at methane conversion 13%) was obtained over a quite wide temperature range of more than 40degreesC at 5.0 MPa and CH4/O-2/N-2 = 100/10/10 (ml/min). The effects of the total flow rate, CH4/O-2 ratio and pressure were examined and the superiority of the new reactor is discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：201 / 207

页数：7

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