Synthesis, spectral and thermal studies of praseodymium(III) and samarium(III) complexes with N,N′,N"-tri(2,4-dihydroxybenzophenone)triaminotriethylamine

被引:0
作者
Thakur, B. G. [1 ]
机构
[1] CM Sc Coll, Dept Chem, Darbhanga 846004, India
关键词
synthesis; Pr(III) and Sm(III) complexes; N,N ',N ''-tri(2,4-dihydroxybenzophenone)triaminotriethylamine;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new Schiff base ligand N,N',N ''-tri(2,4-dihydroxybenzophenone)triaminotriethylamine (H6L) has been synthesized. Its complexation behaviour with praseodymium(III) and samarium(III) have been observed. The complexes has been characterized by elemental analysis, IR spectra molar conductivity measurements and thermal analysis. The praseodymium(III) and samarium(III) cations coordinate with the tridentate Schiff base nitrogen atoms, the bridgehead nitrogen atoms and phenolic hydroxyl oxygen atoms.
引用
收藏
页码:4952 / 4954
页数:3
相关论文
共 11 条
[1]  
DICKSON EFG, 1995, J PHOTOCH PHOTOBIO B, V27, P3
[2]   Syntheses and specific structures of higher-order mixed chelate lanthanide complexes containing terpyridine, acetylacetonate, and nitrate ligands [J].
Fukuda, Y ;
Nakao, A ;
Hayashi, K .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (04) :527-533
[4]   LANTHANIDE-SENSITIZED LUMINESCENCE AND APPLICATIONS TO THE DETERMINATION OF ORGANIC ANALYTES - A REVIEW [J].
GEORGES, J .
ANALYST, 1993, 118 (12) :1481-1486
[5]   Nickel(II) complexes of fully and partially condensed Schiff-base ligands derived from tris(3-aminopropyl)amine and acetylpyridine [J].
Keypour, H ;
Salehzadeh, S ;
Pritchard, RG ;
Parish, RV .
TRANSITION METAL CHEMISTRY, 1998, 23 (05) :605-607
[6]  
MEYER TJ, 2000, COMPREHEN COOR CHEM, V3, P108
[7]  
Nakamoto K., 1978, INFRARED RAMAN SPECT
[8]   Structural systematics of rare earth complexes.: XIV -: Hydrated 1:1 adducts of lanthanoid(III) nitrates with 2,2::6:,2"-terpyridine [J].
Semenova, LI ;
White, AH .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1999, 52 (06) :507-517
[9]   MAGNETIC AND SPECTRAL BEHAVIOR OF CU(II) 55' THIODISALICYCLIC ACID AND MIXED-LIGAND COMPLEXES [J].
SRIVASTAVA, PC ;
BANERJEE, BK .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1980, 42 (12) :1771-1773
[10]  
Vogel AI., 1989, QUANTITATIVE INORGAN