Enhanced thermal conductivity and retained electrical insulation for polyimide composites with SiC nanowires grown on graphene hybrid fillers

被引:132
作者
Dai, Wen [1 ]
Yu, Jinhong [1 ]
Liu, Zhiduo [1 ]
Wang, Yi [1 ]
Song, Yingze [1 ]
Lyu, Jilei [1 ]
Bai, Hua [1 ]
Nishimura, Kazuhito [2 ]
Jiang, Nan [1 ]
机构
[1] Chinese Acad Sci, Nitigbo Inst Mat Technol & Engn, Zhejiang Key Lab Marine Mat & Protect Technol, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China
[2] Kogakuin Univ, Adv Nanoproc Engn Lab, Mech Syst Engn, Tokyo 1920015, Japan
基金
中国国家自然科学基金;
关键词
Hybrid; Polymer-matrix composites (PMCs); Thermal properties; Electrical properties; EPOXY COMPOSITES; BORON-NITRIDE; MECHANICAL-PROPERTIES; POLYMER COMPOSITES; ALUMINUM NITRIDE; NANOCOMPOSITES; SHEETS; FILMS; NANO;
D O I
10.1016/j.compositesa.2015.05.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polyimide (PI) composites containing one-dimensional SiC nanowires grown on two-dimensional graphene sheets (1D-2D SiCNWs-GSs) hybrid fillers were successfully prepared. The PI/SiCNWs-GSs composites synchronously exhibited high thermal conductivity and retained electrical insulation. Moreover, the heat conducting properties of PI/SiCNWs-GSs films present well reproducibility within the temperature range from 25 to 175 degrees C. The maximum value of thermal conductivity of PI composite is 0.577 W/mK with 7 wt% fillers loading, increased by 138% in comparison with that of the neat PI. The 1D SiC nanowires grown on the GSs surface prevent the GSs contacting with each other in the PI matrix to retain electrical insulation of PI composites. In addition, the storage modulus and Young's modulus of PI composites are remarkably improved in comparison with that of the neat PI. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:73 / 81
页数:9
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