Investigations of optical properties of MEH-PPV/ZnO nanocomposites by photoluminescence spectroscopy

被引：31

作者：

Musa, Ishaq ^{[1
]}

Massuyeau, Florian ^{[1
]}

Faulques, Eric ^{[1
]}

Thien-Phap Nguyen ^{[1
]}

机构：

[1] Univ Nantes, CNRS, Inst Mat Jean Rouxel, UMR6502, F-44322 Nantes, France

来源：

SYNTHETIC METALS | 2012年 / 162卷 / 19-20期

关键词：

ZnO nanoparticles; MEH-PPV; UV-Vis spectroscopy; Photoluminescence spectroscopy; Time-resolved photoluminescence; LIGHT-EMITTING DEVICES; ENERGY-TRANSFER; POLYMER;

D O I：

10.1016/j.synthmet.2012.01.011

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The optical properties of hybrid composite films based on poly [2-methoxy-5-(2-ethyl-hexyloxy)-1,4-phenylene-vinylene] (MEH-PPV) and zinc oxide (ZnO) nanoparticles of various sizes (5-20 nm) and with different concentrations have been investigated. The steady-state and time-resolved photoluminescence (PL) spectroscopy have been performed on nanocomposite films at room temperature. The PL results showed a significant enhancement in intensity in nanocomposites when using low nanoparticle concentrations (<5% ZnO). The particle size also impacts on the emission intensity by a larger emission efficiency in thin films containing small particles. In addition, a decrease in the photoluminescence lifetime of MEH-PPV composites has been also observed. Analysis of the time resolved PL decay of nanocomposite films suggests an energy transfer process from the nanoparticles to the polymer chains, in agreement with the steady state measurements. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：1756 / 1761

页数：6

共 22 条

[1] Charge transport in TiO2/MEH-PPV polymer photovoltaics -: art. no. 125205 [J].

Breeze, AJ ;

Schlesinger, Z ;

Carter, SA ;

Brock, PJ .

PHYSICAL REVIEW B, 2001, 64 (12)

[2] Enhanced luminance in polymer composite light emitting devices [J].

Carter, SA ;

Scott, JC ;

Brock, PJ .

APPLIED PHYSICS LETTERS, 1997, 71 (09) :1145-1147

[3] A facile route for preparation of conjugated polymer functionalized inorganic semiconductors and direct application in hybrid photovoltaic devices [J].

Geng, Hongwei ;

Guo, Ying ;

Peng, Ruixiang ;

Han, Shikui ;

Wang, Mingtai .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (07) :1293-1299

[4] Particle surface engineering effect on the mechanical, optical and photoluminescent properties of ZnO/vinyl-ester resin nanocomposites [J].

Guo, Zhanhu ;

Wei, Suying ;

Shedd, Brian ;

Scaffaro, Roberto ;

Pereira, Tony ;

Hahn, H. Thomas .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (08) :806-813

[5] SPECTROELECTROCHEMICAL INVESTIGATIONS OF NANOCRYSTALLINE ZNO FILMS [J].

HOYER, P ;

EICHBERGER, R ;

WELLER, H .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1993, 97 (04) :630-635

[6] Effects of surface modification on the fluorescence properties of conjugated polymer/ZnO nanocomposites [J].

Jetson, Rachael ;

Yin, Kezhen ;

Donovan, Katrina ;

Zhu, Zhengtao .

MATERIALS CHEMISTRY AND PHYSICS, 2010, 124 (01) :417-421

[7] Investigation on the origin of green luminescence from laser-ablated ZnO thin film [J].

Kang, JS ;

Kang, HS ;

Pang, SS ;

Shim, ES ;

Lee, SY .

THIN SOLID FILMS, 2003, 443 (1-2) :5-8

[8] Effect of the method of production of the inorganic matrix on the spectral characteristics of hybrid ZnO/MEH-PPV nanocomposites [J].

Konoshchuk, N. V. ;

Grebinskaya, L. N. ;

Pokhodenko, V. D. .

THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2008, 44 (06) :339-344

[9] Chemical enhancer induced changes in the mechanisms of transdermal delivery of zinc oxide nanoparticles [J].

Kuo, Tsung-Rong ;

Wu, Chung-Long ;

Hsu, Chih-Ting ;

Lo, Wen ;

Chiang, Shu-Jen ;

Lin, Sung-Jan ;

Dong, Chen-Yuan ;

Chen, Chia-Chun .

BIOMATERIALS, 2009, 30 (16) :3002-3008

[10] Traps and performance of MEH-PPV/CdSe(ZnS) nanocomposite-based organic light-emitting diodes [J].

Lee, Chih-Wen ;

Renaud, Cedric ;

Hsu, Chain-Shu ;

Nguyen, Thien-Phap .

NANOTECHNOLOGY, 2008, 19 (45)

← 1 2 3 →