A surfactant-like ionic liquid with permanganate dissolved as a highly selective epoxidation system

被引：5
|
作者：
Lu, Yu-Jing [1 ]
Wong, Wing-Leung [2 ]
Chow, Cheuk-Fai [2 ]
机构：
[1] Guangdong Univ Technol, Inst Nat Med & Green Chem, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China
[2] Hong Kong Inst Educ, Dept Sci & Environm Studies, Ctr Educ Environm Sustainabil, Tai Po, Hong Kong, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2015年 / 69卷
关键词：
Epoxidation; Ionic liquid; Permanganate; POTASSIUM-PERMANGANATE; ALKENE EPOXIDATION; GREEN EPOXIDATION; OXIDATION; CATALYSTS; MILD; HYDROCARBONS; ALCOHOLS; ALKANES; KMNO4;
D O I：
10.1016/j.catcom.2015.05.020
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A ligand-free catalytic epoxidation system using permanganate in a surfactant-like ionic liquid (IL) medium was developed. The results indicate that the IL takes crucial effects in the epoxide selectivity. The loading of permanganate is also found critical in preventing over-oxidation of epoxides. The system with 03 mol% permanganate and 3.5-equivalent CH3CO3H is able to achieve excellent yields and selectivity of epoxides. The study of epoxidation with KMnO4 in IL medium reveals an unusual oxidation behavior of permanganate not found in traditional solvents. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：25 / 28
页数：4
相关论文
共 50 条
  • [31] Study on the mechanism promoting oxidation of long-chain alkanes by self-produced surfactant-like substance at the solid-liquid interface
    Xu, Jinlan
    Li, Fengsen
    Luo, Shengyang
    Shi, Qihang
    Cao, Zezhuang
    Liu, Lu
    Xue, Shujun
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2023, 30 (55) : 117676 - 117687
  • [32] Selective propylene epoxidation in liquid phase using highly dispersed Nb catalysts incorporated in mesoporous silicates
    Wenjuan Yan
    Yuhui Wu
    Xiang Feng
    Chaohe Yang
    Xin Jin
    Jian Shen
    Chinese Journal of Chemical Engineering, 2018, 26 (06) : 1278 - 1284
  • [33] Selective propylene epoxidation in liquid phase using highly dispersed Nb catalysts incorporated in mesoporous silicates
    Yan, Wenjuan
    Wu, Yuhui
    Feng, Xiang
    Yang, Chaohe
    Jin, Xin
    Shen, Jian
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2018, 26 (06) : 1278 - 1284
  • [34] Epoxidation of α, β-unsaturated carbonyl compounds in ionic liquid/water biphasic system under mild conditions
    Wang, B
    Yang, LM
    Suo, JS
    ACTA CHIMICA SINICA, 2003, 61 (02) : 285 - 290
  • [35] Epoxidation of α,β-unsaturated carbonyl compounds in ionic liquid/water biphasic system under mild conditions
    Wang, B
    Kang, YR
    Yang, LM
    Suo, JS
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 203 (1-2) : 29 - 36
  • [36] Enantio-Selective Epoxidation Catalyzed by Supported Sulphonato-Salen-Mn(III) Complex in Ionic Liquid
    Xu Guo-Jin
    Tang Yu-Hai
    Wei Sai-Li
    Sun Yang
    Fu Qiang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (08) : 1359 - 1365
  • [37] Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
    Lepori, Cristian M. O.
    Silber, Juana J.
    Dario Falcone, R.
    Mariano Correa, N.
    RSC ADVANCES, 2017, 7 (71) : 44743 - 44750
  • [38] Study on the mechanism promoting oxidation of long-chain alkanes by self-produced surfactant-like substance at the solid-liquid interface
    Jinlan Xu
    Fengsen Li
    Shengyang Luo
    Qihang Shi
    Zezhuang Cao
    Lu Liu
    Shujun Xue
    Environmental Science and Pollution Research, 2023, 30 : 117676 - 117687
  • [39] Highly sensitive determination and selective immobilization of amoxicillin using carbon ionic liquid electrode
    Ghodratollah Absalan
    Morteza Akhond
    Hamid Ershadifar
    Journal of Solid State Electrochemistry, 2015, 19 : 2491 - 2499
  • [40] Ionic liquid-polyvinyl chloride ionomer for highly selective isolation of basic proteins
    Shu, Yang
    Chen, Xu-Wei
    Wang, Jian-Hua
    TALANTA, 2010, 81 (1-2) : 637 - 642
12345