Directed self-assembly of gradient concentric carbon nanotube rings

Hundreds of gradient concentric rings of linear conjugated polymer, (poly [2-methoxy-5 - (2-ethylhexyloxy)- 1,4- phenylenevinylene],i.e.,MEH-PPV) with remarkable regularity overlarge areas were produced by controlled "stick-slip" motionsof thecontact line in a confined geometry consisting of a sphere on a flat substrate (i.e., sphere-on-flat geometry). Subsequently, MEH-PPV rings were exploited as a template to direct the formation of gradient concentric rings of multiwalled carbon nanotubes (MWNTs) with controlled density. This method is simple, cost effective, and robust, combining two consecutive self-assembly processes, namely, evaporation-induced self-assembly of polymers in a sphere-on-flat geometry, followed by subsequent directed self-assembly of MWNTs on the polymer-templated surfaces.