共 26 条
Electron Beam Mediated Simple Synthetic Route to Preparing Layered Zinc Hydroxide
被引:6
作者:

Bae, Hyo-Sun
论文数: 0 引用数: 0
h-index: 0
机构:
Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul 100715, South Korea Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul 100715, South Korea

论文数: 引用数:
h-index:
机构:
机构:
[1] Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul 100715, South Korea
基金:
新加坡国家研究基金会;
关键词:
Layered hydroxide salts;
Zinc hydroxide nitrate;
Radiolysis;
Electron beam;
RADIATION-INDUCED SYNTHESIS;
DICARBOXYLIC-ACIDS;
NITRATE;
INTERCALATION;
SALTS;
DECOMPOSITION;
SPECTROSCOPY;
DELAMINATION;
D O I:
10.5012/bkcs.2012.33.6.1949
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
We have developed a novel and eco-friendly synthetic route for the preparation of a two-dimensional layered zinc hydroxide with intercalated nitrate anions. The layered zinc hydroxide nitrate, called 'zinc basic salt', was, in general, successfully synthesized, using an electron beam irradiation technique. The 2-propanol solutions containing hydrated zinc nitrate were directly irradiated with an electron-beam at room temperature, under atmospheric conditions, without stabilizers or base molecules. Under electron beam irradiation, the reactive OH. radicals were generated by radiolysis of water molecules in precursor metal salts. After further radiolytic processes, the hydroxyl anions might be formed by the reaction of solvated electrons and the OH. radical. Finally, the Zn-5(OH)(8)(NO3)(2)center dot 2H(2)O was precipitated by the reaction of zinc cation and hydroxyl anions. Structure and morphology of obtained compounds were characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and high resolution transmission electron microscopy (HR-TEM). The chemical components of the products were determined by Fourier transform infrared spectroscopy (FT-IR) and elemental analysis (EA). The thermal behavior of products was studied by thermogravimetric (TG) and differential thermal analysis (DTA).
引用
收藏
页码:1949 / 1954
页数:6
相关论文
共 26 条
- [1] One-Pot Radiolytic Synthesis of Gold Nanorods and Their Optical Properties[J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (35) : 14794 - 14803Abidi, Wafa论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 11, Chim Phys Lab, CNRS, UMR 8000, F-91405 Orsay, France Univ Paris 06, Inst NanoSci Paris, CNRS, UMR 7588, F-75015 Paris, FranceSelvakannan, P. R.论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 11, Chim Phys Lab, CNRS, UMR 8000, F-91405 Orsay, France Univ Paris 06, Inst NanoSci Paris, CNRS, UMR 7588, F-75015 Paris, FranceGuillet, Yanick论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 06, Inst NanoSci Paris, CNRS, UMR 7588, F-75015 Paris, France Univ Bordeaux 1, Mecan Phys Lab, CNRS, UMR 5469, F-33405 Talence, France Univ Paris 06, Inst NanoSci Paris, CNRS, UMR 7588, F-75015 Paris, FranceLampre, Isabelle论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 11, Chim Phys Lab, CNRS, UMR 8000, F-91405 Orsay, France Univ Paris 06, Inst NanoSci Paris, CNRS, UMR 7588, F-75015 Paris, FranceBeaunier, Patricia论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 06, Lab React Surface, CNRS, UMR 7197, F-75252 Paris 05, France Univ Paris 06, Inst NanoSci Paris, CNRS, UMR 7588, F-75015 Paris, France论文数: 引用数: h-index:机构:论文数: 引用数: h-index:机构:Remita, Hynd论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 11, Chim Phys Lab, CNRS, UMR 8000, F-91405 Orsay, France Univ Paris 06, Inst NanoSci Paris, CNRS, UMR 7588, F-75015 Paris, France
- [2] γ-Ray irradiation synthesis and characterization of nickel hydroxide nanoparticles[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2012, 73 (12) : 1456 - 1459Bae, Hyo-Sun论文数: 0 引用数: 0 h-index: 0机构: Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul 100715, South Korea Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul 100715, South KoreaShim, Eun-Ha论文数: 0 引用数: 0 h-index: 0机构: Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul 100715, South Korea Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul 100715, South KoreaPark, Jeong Hoon论文数: 0 引用数: 0 h-index: 0机构: Korea Atom Energy Res Inst, Radiat Res Div Biotechnol, Jeongeup 580185, South Korea Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul 100715, South Korea论文数: 引用数: h-index:机构:
- [3] The role of anhydrous zinc nitrate in the thermal decomposition of the zinc hydroxy nitrates Zn5(OH)8(NO3)2•2H2O and ZnOHNO3•H2O[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (04) : 1171 - 1179Biswick, Timothy论文数: 0 引用数: 0 h-index: 0机构: Univ Cambridge, Dept Chem, Cambridge CB2 1EW, EnglandJones, William论文数: 0 引用数: 0 h-index: 0机构: Univ Cambridge, Dept Chem, Cambridge CB2 1EW, EnglandPacula, Alexandra论文数: 0 引用数: 0 h-index: 0机构: Univ Cambridge, Dept Chem, Cambridge CB2 1EW, EnglandSerwicka, Ewa论文数: 0 引用数: 0 h-index: 0机构: Univ Cambridge, Dept Chem, Cambridge CB2 1EW, EnglandPodobinski, Jerzy论文数: 0 引用数: 0 h-index: 0机构: Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
- [4] P-coumaric acid-zinc basic salt nanohybrid for controlled release and sustained antioxidant activity[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2010, 71 (04) : 647 - 649Biswick, Timothy论文数: 0 引用数: 0 h-index: 0机构: Ewha Womans Univ, CINBM, Dept Bioinspired Sci, Seoul 120750, South Korea Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea Ewha Womans Univ, CINBM, Dept Bioinspired Sci, Seoul 120750, South KoreaPark, Dae-Hwan论文数: 0 引用数: 0 h-index: 0机构: Ewha Womans Univ, CINBM, Dept Bioinspired Sci, Seoul 120750, South Korea Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea Ewha Womans Univ, CINBM, Dept Bioinspired Sci, Seoul 120750, South KoreaShul, Yong-Gun论文数: 0 引用数: 0 h-index: 0机构: Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea Ewha Womans Univ, CINBM, Dept Bioinspired Sci, Seoul 120750, South KoreaChoy, Jin-Ho论文数: 0 引用数: 0 h-index: 0机构: Ewha Womans Univ, CINBM, Dept Bioinspired Sci, Seoul 120750, South Korea Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea Ewha Womans Univ, CINBM, Dept Bioinspired Sci, Seoul 120750, South Korea
- [5] Chemical modification of zinc hydroxide nitrate and Zn-Al-layered double hydroxide with dicarboxylic acids[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 320 (01) : 168 - 176Carbajal Arizaga, Gregorio Guadalupe论文数: 0 引用数: 0 h-index: 0机构: Univ Fed Parana, Lab Quim Estado Solido, Ctr Pesquisas Quim Aplicada, BR-81531990 Curitiba, Parana, Brazil Univ Fed Parana, Lab Quim Estado Solido, Ctr Pesquisas Quim Aplicada, BR-81531990 Curitiba, Parana, BrazilMangrich, Antonio Salvio论文数: 0 引用数: 0 h-index: 0机构: Univ Fed Parana, Lab Projetos & Proc Ambientais, Dept Quim, BR-81531990 Curitiba, Parana, Brazil Univ Fed Parana, Lab Quim Estado Solido, Ctr Pesquisas Quim Aplicada, BR-81531990 Curitiba, Parana, BrazilFerreira da Costa Gardolinski, Jose Eduardo论文数: 0 引用数: 0 h-index: 0机构: Univ Fed Parana, Lab Anal Minerais & Rochas, Dept Geol, BR-81531980 Curitiba, Parana, Brazil Univ Fed Parana, Lab Quim Estado Solido, Ctr Pesquisas Quim Aplicada, BR-81531990 Curitiba, Parana, BrazilWypych, Fernando论文数: 0 引用数: 0 h-index: 0机构: Univ Fed Parana, Lab Quim Estado Solido, Ctr Pesquisas Quim Aplicada, BR-81531990 Curitiba, Parana, Brazil Univ Fed Parana, Lab Quim Estado Solido, Ctr Pesquisas Quim Aplicada, BR-81531990 Curitiba, Parana, Brazil
- [6] Layered hydroxide salts: Synthesis, properties and potential applications[J]. SOLID STATE IONICS, 2007, 178 (15-18) : 1143 - 1162Carbajal Arizaga, Gregorio Guadalupe论文数: 0 引用数: 0 h-index: 0机构: Univ Fed Parana, Dept Chem, BR-81531990 Curitiba, Parana, Brazil Univ Fed Parana, Dept Chem, BR-81531990 Curitiba, Parana, BrazilSatyanarayana, Kestur Gundappa论文数: 0 引用数: 0 h-index: 0机构: Univ Fed Parana, Dept Chem, BR-81531990 Curitiba, Parana, Brazil Univ Fed Parana, Dept Chem, BR-81531990 Curitiba, Parana, BrazilWypych, Fernando论文数: 0 引用数: 0 h-index: 0机构: Univ Fed Parana, Dept Chem, BR-81531990 Curitiba, Parana, Brazil Univ Fed Parana, Dept Chem, BR-81531990 Curitiba, Parana, Brazil
- [7] Anticancer drug encapsulated in inorganic lattice can overcome drug resistance[J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (42) : 9463 - 9469Choi, Soo-Jin论文数: 0 引用数: 0 h-index: 0机构: Seoul Womens Univ, Dept Food Sci & Technol, Seoul 139774, South Korea Ewha Womans Univ, Ctr Intelligent NanoBio Mat, Div Nano Sci BK21, Dept Bioinspired Sci, Seoul 120750, South Korea论文数: 引用数: h-index:机构:论文数: 引用数: h-index:机构:Oh, Yeon-Ji论文数: 0 引用数: 0 h-index: 0机构: Ewha Womans Univ, Ctr Intelligent NanoBio Mat, Div Nano Sci BK21, Dept Bioinspired Sci, Seoul 120750, South Korea Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea Ewha Womans Univ, Ctr Intelligent NanoBio Mat, Div Nano Sci BK21, Dept Bioinspired Sci, Seoul 120750, South KoreaPark, Myung-Chul论文数: 0 引用数: 0 h-index: 0机构: Ewha Womans Univ, Ctr Intelligent NanoBio Mat, Div Nano Sci BK21, Dept Bioinspired Sci, Seoul 120750, South Korea Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea Ewha Womans Univ, Ctr Intelligent NanoBio Mat, Div Nano Sci BK21, Dept Bioinspired Sci, Seoul 120750, South KoreaChoy, Jin-Ho论文数: 0 引用数: 0 h-index: 0机构: Ewha Womans Univ, Ctr Intelligent NanoBio Mat, Div Nano Sci BK21, Dept Bioinspired Sci, Seoul 120750, South Korea Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea Ewha Womans Univ, Ctr Intelligent NanoBio Mat, Div Nano Sci BK21, Dept Bioinspired Sci, Seoul 120750, South Korea
- [8] Characterization of zinc hydroxynitrates by diffuse reflectance infrared spectroscopy - structural modifications during thermal treatment[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2004, 60 (03) : 505 - 511Chouillet, C论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 06, CNRS, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, France Univ Paris 06, CNRS, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, FranceKrafft, JM论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 06, CNRS, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, France Univ Paris 06, CNRS, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, FranceLouis, C论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 06, CNRS, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, France Univ Paris 06, CNRS, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, FranceLauron-Pernot, H论文数: 0 引用数: 0 h-index: 0机构: Univ Paris 06, CNRS, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, France Univ Paris 06, CNRS, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, France
- [9] Layered zinc hydroxide salts: Delamination, preferred orientation of hydroxide lamellae, and formation of ZnO nanodiscs[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 360 (02) : 532 - 539Demel, Jan论文数: 0 引用数: 0 h-index: 0机构: Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech Republic Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech RepublicPlestil, Josef论文数: 0 引用数: 0 h-index: 0机构: Acad Sci Czech Republic, Inst Macromol Chem, VVI, CR-16206 Prague, Czech Republic Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech RepublicBezdicka, Petr论文数: 0 引用数: 0 h-index: 0机构: Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech Republic Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech RepublicJanda, Pavel论文数: 0 引用数: 0 h-index: 0机构: Acad Sci Czech Republic, J Heyrovsky Inst Phys Chem, CR-18223 Prague, Czech Republic Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech RepublicKlementova, Mariana论文数: 0 引用数: 0 h-index: 0机构: Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech Republic Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech RepublicLang, Kamil论文数: 0 引用数: 0 h-index: 0机构: Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech Republic Acad Sci Czech Republic, Inst Inorgan Chem, VVI, CZ-25068 Rez, Czech Republic
- [10] The electrochemical performance of ordered mesoporous carbon/nickel compounds composite material for supercapacitor[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (12) : 2932 - 2936Feng, Jicheng论文数: 0 引用数: 0 h-index: 0机构: Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R ChinaZhao, Jiachang论文数: 0 引用数: 0 h-index: 0机构: Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R ChinaTang, Bohejin论文数: 0 引用数: 0 h-index: 0机构: Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R ChinaLiu, Ping论文数: 0 引用数: 0 h-index: 0机构: Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R ChinaXu, Jingli论文数: 0 引用数: 0 h-index: 0机构: Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China