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Development and Industrialization of Efficient Cross-Coupling Reactions
被引:3
|作者:
Eguchi, Hisao
[1
]
Nishiyama, Masakazu
[2
]
Ishikawa, Shin-ichi
[2
]
Soga, Shin-ichi
[1
]
Koie, Yasuyuki
[2
]
机构:
[1] Tosoh Organ Chem Co Ltd, Shunan 7460006, Japan
[2] Tosoh Corp, Shunan 7468501, Japan
关键词:
cross-coupling;
Buchwald-Hartwig coupling;
Suzuki-Miyaura coupling;
Kumada-Tamao coupling;
palladium catalyst;
tri(tert-butyl) phosphine;
nickel catalyst;
iron catalyst;
aryl chloride;
triarylamine;
unsymmetrical biaryl;
styrene derivative;
ARYLBORONIC ACIDS;
ARYL;
HALIDES;
CATALYSTS;
BIARYLS;
D O I:
10.5059/yukigoseikyokaishi.70.937
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Ttransition-metal catalyzed cross-coupling reactions (C-C, C-N) are the useful and powerful tools for the synthesis of OLED (organic light-emitting diode) or LCD (liquid crystal display) materials. For many years, a major drawback of this reaction has been the poor reactivity of aryl chloride, which are more attractive in terms of cost and availability than the corresponding bromide, iodide and triflate. This review summarized the recent developments combined with our work utilizing the aryl chloride in this area.
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页码:937 / 946
页数:10
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