Porous structure of polyarylamide-based activated carbon fibres

被引:66
作者
Stoeckli, F [1 ]
Centeno, TA [1 ]
Fuertes, AB [1 ]
Muniz, J [1 ]
机构
[1] CSIC,INST NACL CARBON,E-33080 OVIEDO,SPAIN
关键词
activated fibres; microporosity; molecular-sieve properties;
D O I
10.1016/0008-6223(96)00088-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Activated carbons were prepared from two polyarylamide fibres (Kevlar and Nomex) by carbonization and subsequent steam activation to 25 and 50% burn-off. The porous structure of the carbons has been investigated by physical adsorption of CH2Cl2 and N2O at 293 K and immersion calorimetry into liquids of different molecular dimensions. The activated fibres have good sorptive capacities and relatively narrow micropores. The materials resulting from activation at low degrees of burn-off could therefore be of great interest in gas separation, owing to their molecular-sieve properties. Compared to industrial activated carbons, the fibres are hydrophilic and have small external surface areas. Copyright (C) 1996 Published by Elsevier Science Ltd
引用
收藏
页码:1201 / 1206
页数:6
相关论文
共 19 条
[1]  
Bansal R.C., 1988, ACTIVE CARBON
[2]   THE OXIDATION OF AN ASTURIAN BITUMINOUS COAL IN AIR AND ITS INFLUENCE ON SUBSEQUENT ACTIVATION BY STEAM [J].
CENTENO, TA ;
STOECKLI, F .
CARBON, 1995, 33 (05) :581-586
[4]   ADSORPTION OF NITROGEN AND WATER-VAPOR BY ACTIVATED NOMEX(R) CHARS [J].
FREEMAN, JJ ;
TOMLINSON, JB ;
SING, KSW ;
THEOCHARIS, CR .
CARBON, 1995, 33 (06) :795-799
[5]  
FREEMAN JJ, 1991, CHARACTERISATION POR, V2, P319
[6]  
FREEMAN JJ, 1991, 20 BIENN C CARB SANT, P98
[7]   CARBON MOLECULAR-SIEVES - PRODUCTION FROM COAL AND APPLICATION IN GAS SEPARATION [J].
JUNTGEN, H ;
KNOBLAUCH, K ;
HARDER, K .
FUEL, 1981, 60 (09) :817-822
[8]   THE USE OF IMMERSION CALORIMETRY IN THE DETERMINATION OF MICROPORE DISTRIBUTION OF CARBONS IN THE COURSE OF ACTIVATION [J].
KRAEHENBUEHL, F ;
STOECKLI, HF ;
ADDOUN, A ;
EHRBURGER, P ;
DONNET, JB .
CARBON, 1986, 24 (04) :483-488
[9]   ON THE ADSORPTION OF CO2 BY MOLECULAR-SIEVE CARBONS - VOLUMETRIC AND GRAVIMETRIC STUDIES [J].
NAKASHIMA, M ;
SHIMADA, S ;
INAGAKI, M ;
CENTENO, TA .
CARBON, 1995, 33 (09) :1301-1306
[10]  
PIGLIACAMPI JJ, 1989, ENG MAT HDB, V1, P114