Nano-crystallization of Fe36Cr12Mo10 phase in Fe55-xCr18Mo7B16C4Nbx (X=0, 3, 4) amorphous alloys

被引:10
作者
Ahmadi, S. [1 ]
Shahverdi, H. R. [1 ]
Afsari, M. [1 ]
Abdollah-zadeh, Amir [1 ]
机构
[1] Tarbiat Modares Univ, Fac Engn, Dept Mat Engn, Tehran, Iran
关键词
Bulk amorphous steels (BASs); Structural amorphous steels (SASs); Bulk amorphous metals (BAMs); Crystallization; Kinetic models; BULK GLASSY ALLOYS; METALLIC-GLASS; KINETICS; CR;
D O I
10.1016/j.jnoncrysol.2012.11.032
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Crystallization of nanosize Fe36Cr12Mo10 phase during annealing process of amorphous Fe55-xCr18Mo7B16C4Nbx (X=0, 3, 4) alloys and also growth mechanisms were studied by X-ray diffraction and differential scanning calorimetric tests as well as TEM observations. Results of TEM observations showed that Fe36Cr12Mo10 phase crystallized in the structures of the alloys in separated perlitic colonies. Furthermore, it is proposed that Fe36Cr12Mn10 phase crystallized in the alloys in mottled morphology and about average size of 10 nm. In addition, kinetic investigations revealed that not only nucleation frequencies but also growth rates were reduced simultaneously by Nb alloying in the alloys. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:47 / 52
页数:6
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