Nb2O5-carbon core-shell nanocomposite as anode material for lithium ion battery

被引:0
作者
Li, Ge [1 ,2 ]
Wang, Xiaolei [2 ]
Ma, Xueming [1 ]
机构
[1] E China Normal Univ, Dept Phys, Shanghai 200241, Peoples R China
[2] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA
关键词
niobium pentoxide; core-shell; long cycle life; high performance anode; lithium ion battery; NB2O5; PERFORMANCE; FRAMEWORK; FILMS;
D O I
暂无
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Nb2O5-carbon nanocomposite is synthesized through a facile one-step hydrothermal reaction from sucrose as the carbon source, and studied as an anode material for high-performance lithium ion battery. The structural characterizations reveal that the nanocomposite possesses a core-shell structure with a thin layer of carbon shell homogeneously coated on the Nb2O5 nanocrystals. Such a unique structure enables the composite electrode with a long cycle life by preventing the Nb2O5 from volume change and pulverization during the charge-discharge process. In addition, the carbon shell efficiently improves the rate capability. Even at a current density of 500 mA.g(-1), the composite electrode still exhibits a specific capacity of similar to 100 mAh.g(-1). These results suggest the possibility to utilize the Nb2O5-carbon core-shell composite as a high performance anode material in the practical application of lithium ion battery.
引用
收藏
页码:357 / 362
页数:6
相关论文
共 20 条
[1]   Sol-gel niobium pentoxide: A promising material for electrochromic coatings, batteries, nanocrystalline solar cells and catalysis [J].
Aegerter, MA .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 68 (3-4) :401-422
[2]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[3]   Templated Nanocrystal-Based Porous TiO2 Films for Next-Generation Electrochemical Capacitors [J].
Brezesinski, Torsten ;
Wang, John ;
Polleux, Julien ;
Dunn, Bruce ;
Tolbert, Sarah H. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1802-1809
[4]   Single-Step Synthesis of Nanosized Titanium-Based Oxide/Carbon Nanotube Composites by Electrospray Deposition and Their Electrochemical Properties [J].
Doi, Takayuki ;
Miwa, Yohei ;
Iriyama, Yasutoshi ;
Abe, Takeshi ;
Ogumi, Zempachi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (18) :7719-7722
[5]   Synthesis and characterization of Nb2O5@C core-shell nanorods and Nb2O5 nanorods by reacting Nb(OEt)5 via RAPET (reaction under autogenic pressure at elevated temperatures) technique [J].
George, P. P. ;
Pol, V. G. ;
Gedanken, A. .
NANOSCALE RESEARCH LETTERS, 2007, 2 (01) :17-23
[6]   3-V Full Cell Performance of Anode Framework TiNb2O7/Spinel LiNi0.5Mn1.5O4 [J].
Han, Jian-Tao ;
Goodenough, John B. .
CHEMISTRY OF MATERIALS, 2011, 23 (15) :3404-3407
[7]   New Anode Framework for Rechargeable Lithium Batteries [J].
Han, Jian-Tao ;
Huang, Yun-Hui ;
Goodenough, John B. .
CHEMISTRY OF MATERIALS, 2011, 23 (08) :2027-2029
[8]   Microscale spherical carbon-coated Li4Ti5O12 as ultra high power anode material for lithium batteries [J].
Jung, Hun-Gi ;
Myung, Seung-Taek ;
Yoon, Chong Seung ;
Son, Seoung-Bum ;
Oh, Kyu Hwan ;
Amine, Khalil ;
Scrosati, Bruno ;
Sun, Yang-Kook .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (04) :1345-1351
[9]   Electrochemical and in situ XAFS-XRD investigation of Nb2O5 for rechargeable lithium batteries [J].
Kodama, R ;
Terada, Y ;
Nakai, I ;
Komaba, S ;
Kumagai, N .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (03) :A583-A588
[10]   Nanostructured Nb2O5 Polymorphs by Electrospinning for Rechargeable Lithium Batteries [J].
Le Viet, A. ;
Reddy, M. V. ;
Jose, R. ;
Chowdari, B. V. R. ;
Ramakrishna, S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (01) :664-671