Structural and optical properties of sulfurized Cu2ZnSnS4 thin films from Cu-Zn-Sn alloy precursors

被引：24

作者：

Amal, M. Ikhlasul ^{[1
]}

Kim, Kyoo Ho ^{[1
]}

机构：

[1] Yeungnam Univ, Dept Mat Sci & Engn, Gyongsan 712749, Gyeongbuk, South Korea

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2013年 / 24卷 / 02期

关键词：

SOLAR-CELLS; CONSTANTS; THICKNESS; GROWTH;

D O I：

10.1007/s10854-012-0858-7

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

This study reports the preparation of Cu2ZnSnS4 (CZTS) thin films by magnetron sputtering deposition with a Cu-Zn-Sn ternary alloy target and sequential sulfurization. The effects of substrate temperatures on the structural, morphological, compositional as well as optical and electrical properties were characterized. The results showed the CZTS thin films prepared by sulfurization at substrate temperature of 570 A degrees C yielded secondary phases along with CZTS compound. The relatively good properties of CZTS thin film were obtained after sulfurization at substrate temperature of 550 A degrees C. This CZTS film showed compact structure with large grain size of 900 nm, direct optical band gap of 1.47 eV, optical absorption coefficient over 10(4) cm(-1), resistivity of 4.05 Omega cm, carrier concentration of 8.22 x 10(18) cm(-3), and mobility of 43.38 cm(2) V-1 S-1.

引用

页码：559 / 566

页数：8

共 21 条

[1] Preparationof Cu2ZnSnS4 thin films by sulfurization of co-electroplated Cu-Zn-Sn precursors
Araki, Hideaki
Kubo, Yuki
Jimbo, Kazuo
Maw, Win Shwe
Katagiri, Hironori
Yamazaki, Makoto
Oishi, Koichiro
Takeuchi, Akiko
[J]. PHYSICA STATUS SOLIDI C - CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 6, NO 5, 2009, 6 (05): : 1266 - 1268
[2] Cu2ZnSnS4 thin film solar cells from electroplated precursors: Novel low-cost perspective
Ennaoui, A.
Lux-Steiner, M.
Weber, A.
Abou-Ras, D.
Koetschau, I.
Schock, H. -W.
Schurr, R.
Hoelzing, A.
Jost, S.
Hock, R.
Voss, T.
Schulze, J.
Kirbs, A.
[J]. THIN SOLID FILMS, 2009, 517 (07) : 2511 - 2514
[3] Fabrication of Cu(In,Ga)Se2 thin films by ion beam sputtering deposition from a quaternary target at different substrate temperatures
Fan, Ping
Chi, Jing-rong
Liang, Guang-xing
Cai, Xing-min
Zhang, Dong-ping
Zheng, Zhuang-hao
Cao, Peng-ju
Chen, Tiao-bao
[J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2012, 23 (11) : 1957 - 1960
[4] A study of ternary Cu2SnS3 and Cu3SnS4 thin films prepared by sulfurizing stacked metal precursors
Fernandes, P. A.
Salome, P. M. P.
da Cunha, A. F.
[J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (21)
[5] Growth and Raman scattering characterization of Cu2ZnSnS4 thin films
Fernandes, P. A.
Salome, P. M. P.
da Cunha, A. F.
[J]. THIN SOLID FILMS, 2009, 517 (07) : 2519 - 2523
[6] Johnson J.L., 2011, J ELECT MAT, V40, P11
[7] Growth of Cu2ZnSnSe4 Thin Films by Selenization of Sputtered Single-Layered Cu-Zn-Sn Metallic Precursors from a Cu-Zn-Sn Alloy Target
Kim, Kyoo-Ho
Amal, Ikhlasul
[J]. ELECTRONIC MATERIALS LETTERS, 2011, 7 (03) : 225 - 230
[8] Investigation of Cu2ZnSnS4-based thin film solar cells using abundant materials
Kobayashi, T
Jimbo, K
Tsuchida, K
Shinoda, S
Oyanagi, T
Katagiri, H
[J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (1B): : 783 - 787
[9] Cu(In,Ga)Se2 films prepared by sputtering with a chalcopyrite Cu(In,Ga)Se2 quaternary alloy and In targets
Lin, Y. C.
Lin, Z. Q.
Shen, C. H.
Wang, L. Q.
Ha, C. T.
Peng, Chris
[J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2012, 23 (02) : 493 - 500
[10] SIMPLE METHOD FOR DETERMINATION OF OPTICAL-CONSTANTS N,K AND THICKNESS OF A WEAKLY ABSORBING THIN-FILM
MANIFACIER, JC
GASIOT, J
FILLARD, JP
[J]. JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1976, 9 (11): : 1002 - 1004

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