Synthesis and characterisation of the first unidimensional cobalt hydrogen phosphate, [H3N(CH2)3NH3][Co(HPO4)2]

被引：47

作者：

Cowley, AR ^{[1
]}

Chippindale, AM ^{[1
]}

机构：

[1] Univ Oxford, Chem Crystallog Lab, Oxford OX1 3PD, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 13期

关键词：

D O I：

10.1039/a901469a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first unidimensional organically templated cobalt hydrogenphosphate, [H3N(CH2)(3)NH3][Co(HPO4)(2)], has been synthesized at 433 K under solvothermal conditions in the presence of 1,3-diaminopropane and the structure determined at 150 K using single-crystal X-ray diffraction. The compound contains anionic chains of formula [Co(HPO4)(2)](2-) constructed from edge-sharing 4-membered rings of alternating CoO4 and HPO4 tetrahedra from which hang additional "pendant" HPO4 groups. The chains, which are structurally similar to those found recently in unidimensional aluminophosphates, are held together by a network of hydrogen bonds involving both interchain and chain-diamine interactions.

引用

页码：2147 / 2149

页数：3

共 15 条

[1]

ALTOMARE A, 1994, J APPL CRYSTALLOGR, V27, P453

[2]

[Anonymous], CRYSTALS USER GUIDE

[3]

CHEN JS, 1994, ANGEW CHEM INT EDIT, V33, P639, DOI 10.1002/anie.199406391

[4] The synthesis and characterization of a one-dimensional aluminophosphate: [C10N2H9] [Al(PO4)(PO2(OH)(2))] [J].

Chippindale, AM ;

Turner, C .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 128 (02) :318-322

[5] The first organically templated layered cobalt phosphates: Hydrothermal syntheses and crystal structures of [H3N(CH2)(3)NH3](0.5)[Co(PO4)]center dot 0.5H2O and [H3N(CH2)(4)NH3](0.5)[Co(PO4)] [J].

DeBord, JRD ;

Haushalter, RC ;

Zubieta, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1996, 125 (02) :270-273

[6] STRUCTURE OF PROPANE-1,3-DIAMMONIUM MONOHYDROMONOPHOSPHATE MONOHYDRATE [J].

KAMOUN, S ;

JOUINI, A ;

DAOUD, A .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :117-119

[7] Large tunnels in the hydrothermally synthesized open-framework iron phosphate [H3N(CH2)(3)NH3](2)[Fe-4(OH)(3)(HPO4)(2)(PO4)(3)]center dot xH(2)O [J].

Lii, KH ;

Huang, YF .

CHEMICAL COMMUNICATIONS, 1997, (09) :839-840

[8] Preparation and crystal structure of a new gallium phosphate [H3N(CH2)(3)NH3](2+)[GaH(PO4)(2)](2-) from water-Me2SO [J].

Loiseau, T ;

Serpaggi, F ;

Ferey, G .

CHEMICAL COMMUNICATIONS, 1997, (12) :1093-1094

[9] Synthesis and structure of a three-dimensional open-framework aluminophosphate [NH2(CH2)(3)NH3](+)[HAl3P3O14](-)center dot H2O, containing AlO5 and AlO6 polyhedra [J].

Natarajan, S ;

Gabriel, JCP ;

Cheetham, AK .

CHEMICAL COMMUNICATIONS, 1996, (12) :1415-1416

[10] Aluminophosphate chain-to-layer transformation [J].

Oliver, S ;

Kuperman, A ;

Lough, A ;

Ozin, GA .

CHEMISTRY OF MATERIALS, 1996, 8 (09) :2391-2398

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