Large-Scale Colloidal Synthesis of Non-Stoichiometric Cu2ZnSnSe4 Nanocrystals for Thermoelectric Applications

被引:130
作者
Fan, Feng-Jia [1 ]
Wang, Yi-Xiu [1 ]
Liu, Xiao-Jing [1 ]
Wu, Liang [1 ]
Yu, Shu-Hong [1 ]
机构
[1] Univ Sci & Technol China, Div Nanomat & Chem, Hefei Natl Lab Phys Sci Microscale, Dept Chem,Natl Synchrotron Radiat Lab, Hefei 230026, Anhui, Peoples R China
基金
对外科技合作项目(国际科技项目); 中国国家自然科学基金;
关键词
scale-up syntheses; Cu2ZnSnSe4; Cu2SnSe3; nanocrystals; thermoelectrics; FIGURE-OF-MERIT; NANOSTRUCTURED THERMOELECTRICS; BULK ALLOYS; PERFORMANCE; NANOPARTICLES; CU2CDSNSE4; DISTORTION;
D O I
10.1002/adma.201202860
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Over 10 g of non-stoichiometric Cu2ZnSnSe4 colloidal nanocrystals for thermoelectric applications are prepared after one single reaction. The obtained pellet made from the colloidal nanocrystals shows a peak ZT value of 0.44 at 450 degrees C, which is similar to those of state-of-the- art Cu2ZnSnSe4-based bulk materials at the same temperature.
引用
收藏
页码:6158 / 6163
页数:6
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