Two dimensional α-MoO3 nanosheets decorated carbon cloth electrodes for high-performance supercapacitors

被引:56
|
作者
Murugesan, D. [1 ]
Prakash, S. [2 ]
Ponpandian, N. [2 ]
Manisankar, P. [2 ]
Viswanathan, C. [1 ]
机构
[1] Bharathiar Univ, Dept Nanosci & Technol, Coimbatore 641046, Tamil Nadu, India
[2] Alagappa Univ, Dept Ind Chem, Karaikkudi 630003, Tamil Nadu, India
关键词
Nanosheets; MoO3; Surface; Supercapacitor; High capacity; THIN-FILMS; COMPOSITE ELECTRODES; ELECTROCHEMICAL PERFORMANCE; SOLVOTHERMAL SYNTHESIS; HYDROTHERMAL SYNTHESIS; MOLYBDENUM OXIDE; ENERGY-STORAGE; NANOTUBE; DEPOSITION; NANORODS;
D O I
10.1016/j.colsurfa.2019.02.062
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The production of two dimensional (2D) layers, especially nanosheet is of significant importance to develop supercapacitors. Herein, reactive radio-frequency magnetron sputtering method is employed to the 2D alpha-MoO3 nanosheet preparations on carbon cloth substrate. As-prepared 2D alpha-MoO3 nanosheet coated carbon cloth has been characterized by XRD, UV-vis, Raman, FE-SEM, EDX techniques. Supercapacitor performance of 2D alpha-MoO(3 )nanosheet coated carbon cloth is tested from cyclic voltammetry (CV) and galvanostatic charge discharge (GCD) techniques in 1.0 M aqueous Na2SO4 electrolyte. 2D alpha-MoO3 nanosheet coated carbon cloth delivers the specific capacitance 240 F g(-1) at current density of 1.5 mA cm(-2) with capacity retention of 78.8% for 5000 cycles at 2.5 mA cm(-2 ). Compared to bare carbon cloth and alpha-MoO(3 )decorated carbon cloth at room temperature, 2D alpha-MoO3 nanosheet coated carbon cloth exhibits much higher specific capacity, superior cyclability, and good rate capability, highlighting the advantages of hierarchical nanosheet and high surface area in the MoO3 structure.
引用
收藏
页码:137 / 144
页数:8
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