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Two dimensional α-MoO3 nanosheets decorated carbon cloth electrodes for high-performance supercapacitors
被引:56
|作者:
Murugesan, D.
[1
]
Prakash, S.
[2
]
Ponpandian, N.
[2
]
Manisankar, P.
[2
]
Viswanathan, C.
[1
]
机构:
[1] Bharathiar Univ, Dept Nanosci & Technol, Coimbatore 641046, Tamil Nadu, India
[2] Alagappa Univ, Dept Ind Chem, Karaikkudi 630003, Tamil Nadu, India
关键词:
Nanosheets;
MoO3;
Surface;
Supercapacitor;
High capacity;
THIN-FILMS;
COMPOSITE ELECTRODES;
ELECTROCHEMICAL PERFORMANCE;
SOLVOTHERMAL SYNTHESIS;
HYDROTHERMAL SYNTHESIS;
MOLYBDENUM OXIDE;
ENERGY-STORAGE;
NANOTUBE;
DEPOSITION;
NANORODS;
D O I:
10.1016/j.colsurfa.2019.02.062
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The production of two dimensional (2D) layers, especially nanosheet is of significant importance to develop supercapacitors. Herein, reactive radio-frequency magnetron sputtering method is employed to the 2D alpha-MoO3 nanosheet preparations on carbon cloth substrate. As-prepared 2D alpha-MoO3 nanosheet coated carbon cloth has been characterized by XRD, UV-vis, Raman, FE-SEM, EDX techniques. Supercapacitor performance of 2D alpha-MoO(3 )nanosheet coated carbon cloth is tested from cyclic voltammetry (CV) and galvanostatic charge discharge (GCD) techniques in 1.0 M aqueous Na2SO4 electrolyte. 2D alpha-MoO3 nanosheet coated carbon cloth delivers the specific capacitance 240 F g(-1) at current density of 1.5 mA cm(-2) with capacity retention of 78.8% for 5000 cycles at 2.5 mA cm(-2 ). Compared to bare carbon cloth and alpha-MoO(3 )decorated carbon cloth at room temperature, 2D alpha-MoO3 nanosheet coated carbon cloth exhibits much higher specific capacity, superior cyclability, and good rate capability, highlighting the advantages of hierarchical nanosheet and high surface area in the MoO3 structure.
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页码:137 / 144
页数:8
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