Triple self-condensation of ketones yielding aromatics promoted with titanium tetrachloride

被引:32
作者
Li, ZL
Sun, WH [1 ]
Jin, XL
Shao, CX
机构
[1] Chinese Acad Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China
[2] Beijing Univ, Inst Phys Chem, Beijing 100871, Peoples R China
关键词
ketones; self-condensation; titanium tetrachloride; substituted benzene; enolate;
D O I
10.1055/s-2001-18771
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Triple self-condensation of ketones was promoted by, titanium tetrachloride in toluene to afford corresponding benzene derivatives, and the structure of tri(2-naphthyl)benzene was confirmed by X-ray single crystal diffraction.
引用
收藏
页码:1947 / 1949
页数:3
相关论文
共 10 条
[1]   INVESTIGATIONS OF THE TETRACHLOROSILANE-ETHANOL INDUCED SELF CONDENSATIONS OF KETONES [J].
ELMORSY, SS ;
PELTER, A ;
SMITH, K ;
HURSTHOUSE, MB ;
ANDO, D .
TETRAHEDRON LETTERS, 1992, 33 (06) :821-824
[2]   THE DIRECT PRODUCTION OF TRI-SUBSTITUTED AND HEXA-SUBSTITUTED BENZENES FROM KETONES UNDER MILD CONDITIONS [J].
ELMORSY, SS ;
PELTER, A ;
SMITH, K .
TETRAHEDRON LETTERS, 1991, 32 (33) :4175-4176
[3]   NEW PROCEDURE FOR THE DIRECT GENERATION OF TITANIUM ENOLATES - DIASTEREOSELECTIVE BOND CONSTRUCTIONS WITH REPRESENTATIVE ELECTROPHILES [J].
EVANS, DA ;
URPI, F ;
SOMERS, TC ;
CLARK, JS ;
BILODEAU, MT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (22) :8215-8216
[4]  
GALLI P, 1999, METALORGANIC CATALYS, P14
[5]   KNOEVENAGEL CONDENSATIONS WITH TICL4/BASE .3. REACTIONS OF KETONES AND ALPHA HALOGEN KETONES WITH MALONIC ESTERS [J].
LEHNERT, W .
TETRAHEDRON, 1973, 29 (04) :635-638
[6]  
MAZZA LJ, 1980, SYNTHESIS-STUTTGART, P41
[7]   Catalytic asymmetric organozinc additions to carbonyl compounds [J].
Pu, L ;
Yu, HB .
CHEMICAL REVIEWS, 2001, 101 (03) :757-824
[8]   Synthetic principles for bandgap control in linear pi-conjugated systems [J].
Roncali, J .
CHEMICAL REVIEWS, 1997, 97 (01) :173-205
[9]   Structure/energy correlation of bowl depth and inversion barrier in corannulene derivatives: Combined experimental and quantum mechanical analysis [J].
Seiders, TJ ;
Baldridge, KK ;
Grube, GH ;
Siegel, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (04) :517-525
[10]   Shape and size effects in the crystal structures of complexes of 1,3,5-trinitrobenzene with some trigonal donors: The benzene-thiophene exchange rule [J].
Thallapally, PK ;
Chakraborty, K ;
Carrell, HL ;
Kotha, S ;
Desiraju, GR .
TETRAHEDRON, 2000, 56 (36) :6721-6728