A debut for base stabilized monoalkylsilylenes

被引：54
作者：
Azhakar, Ramachandran [1 ]
Ghadwal, Rajendra S. [1 ]
Roesky, Herbert W. [1 ]
Wolf, Hilke [1 ]
Stalke, Dietmar [1 ]
机构：
[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 38期
关键词：
N-HETEROCYCLIC CARBENE; METAL-CARBONYL-COMPLEXES; SILICON DIFLUORIDE; SILYLENE; LIGANDS; REACTIVITY; CHEMISTRY; DICHLOROSILYLENE; CHLOROSILYLENE; ACTIVATION;
D O I：
10.1039/c2cc31041d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first base stabilized monoalkylsilylenes LSitBu (2) and LSi[C(SiMe3)(3)] (3) (L = PhC(NtBu)(2)) were synthesized by the facile metathesis reactions of LitBu and KC(SiMe3)(3) with LSiCl (1). The reaction of LSitBu (2) with N2O afforded the dimer [LSitBu(mu-O)](2) (4) which contains a four-membered Si2O2 ring.
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收藏
页码：4561 / 4563
页数：3
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