Direct growth of Cu3(BTC)2(H2O)3•xH2O thin films on modified QCM-gold electrodes -: Water sorption isotherms

被引：162
|
作者：
Biemmi, Enrica [1 ]
Darga, Alexander [1 ]
Stock, Norbert [2 ]
Bein, Thomas [1 ]
机构：
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
[2] Univ Kiel, Inst Inorgan Chem, D-24118 Kiel, Germany
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2008年 / 114卷 / 1-3期
关键词：
metal-organic framework; thin film; self-assembled monolayer; quartz crystal microbalance; water sorption isotherm;
D O I：
10.1016/j.micromeso.2008.01.024
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The preparation of a thin film of the metal-organic framework Cu-3(BTC)(2)(H2O)(3)center dot xH(2)O (HKUST-1) on the gold electrode of a quartz-crystal microbalance (QCM) was achieved by direct growth on a 11-mercaptoundecanol self-assembled monolayer (SAM). The formation of the SAM on the gold substrate was proven via reflection-absorption infrared-spectroscopy. The HKUST-1 thin film was characterized by X-ray diffraction, Raman-spectroscopy, and scanning-electron microscopy. Water vapor sorption measurements allow us to directly characterize the sorption properties of the thin film grown on the electrode of the QCM-device. (C) 2008 Elsevier Inc. All rights reserved.
引用
收藏
页码：380 / 386
页数：7
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