Spatial organization in the A+B->0 reaction under confined-scale mixing

被引:12
|
作者
Reigada, R
Sagues, F
Sokolov, IM
Sancho, JM
Blumen, A
机构
[1] UNIV FREIBURG,D-79104 FREIBURG,GERMANY
[2] PN LEBEDEV PHYS INST,MOSCOW 117924,RUSSIA
[3] UNIV BARCELONA,DEPT ESTRUCTURA & CONSTITUENTS MAT,BARCELONA 08028,SPAIN
来源
JOURNAL OF CHEMICAL PHYSICS | 1997年 / 107卷 / 03期
关键词
D O I
10.1063/1.474470
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We consider the kinetics of the two-dimensional, stoichiometric A+B-->O reaction under confined-scale turbulent mixing and concentrate on the interplay between the kinetic patterns and the spatial organization of the system. We study the properties of the arising clusters and of the reaction zones, both in the presence and in the absence of mixing. We show that the two-point correlation function C-AB(r)=[c(A)(r'+r)c(B)(r')]/[c(A)(r)](2) is closely related to the effective reaction rate, while the functional form of the quartic correlation function Q(r,t) =[c(A)(r',t)c(B)(r',t)c(A)(r'+r,t)c(B)(r'+r.t)]/[c(A)(2)(r,t)c(B)(2)(r,t)] is connected to the geometry of the reaction zones. We pay special attention to the occurrence of time windows of fast (classical) concentration decay even when the reactants show strong segregation. (C) 1997 American Institute of Physics.
引用
收藏
页码:843 / 848
页数:6
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