Structure-function relationships in conjugated materials containing tunable thieno[3,4-b]pyrazine units

被引：5
|
作者：
Mulholland, Michael E. [1 ]
Schwiderski, Ryan L. [1 ]
Rasmussen, Seth C. [1 ]
机构：
[1] N Dakota State Univ, NDSU Dept 2735, Dept Chem & Biochem, Fargo, ND 58108 USA
来源：
POLYMER BULLETIN | 2012年 / 69卷 / 03期
基金：
美国国家科学基金会;
关键词：
Conjugated polymers; Thieno[3,4-b]pyrazine; Structure-function relationships; Electronic tuning; POLYMERS; DONOR; POLYFLUORENES; COPOLYMER; DESIGN;
D O I：
10.1007/s00289-012-0718-x
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of 2,3-difunctionalized 5,7-bis(2-thienyl)thieno[3,4-b]pyrazines containing electron-donating and electron-withdrawing side chains are reported to evaluate the potential tuning effect of the side chains on the electronic properties of these common terthienyl building blocks. In order to further study the resulting effects of such side chains in polymeric materials, the dihexyloxy-functionalized terthienyl was copolymerized with fluorene and its electronic properties compared with a number of analogous materials.
引用
收藏
页码：291 / 301
页数：11
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