Synthesis and characterization of amido and amido(monoalkylamido)nitrosyl[tris(3,5-dimethylpyrazolyl)borato]molybdenum complexes

被引：1
作者：
Topaloglu, I [1 ]
McCleverty, JA [1 ]
机构：
[1] UNIV BRISTOL,SCH CHEM,BRISTOL,AVON,ENGLAND
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 08期
关键词：
D O I：
10.1080/00945719708000258
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl(NH2)] was prepared by treating [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl-2] with an excess of ammonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)(3)}-(NO)(NH2)(NHR)] (R = Me, Et, Pr-(n) under bar and Bu-(n) under bar) were obtained by the reaction of [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl(NH2)] with the appropriate primary amines. The IR and H-1 NMR spectra of the new complexes were investigated.
引用
收藏
页码：1205 / 1217
页数：13
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