Elucidating the paramagnetic interactions of an inorganic-organic hybrid radical-functionalized Mn-Anderson cluster

被引：9

作者：

Lin, Chang-Gen ^{[1
,2
]}

Hutin, Marie ^{[1
]}

Busche, Christoph ^{[1
]}

Bell, Nicola L. ^{[1
]}

Long, De-Liang ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

[2] Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 07期

基金：

英国工程与自然科学研究理事会; 中国国家自然科学基金;

关键词：

Paramagnetism;

D O I：

10.1039/d0dt04149a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A family of six polyoxometalate-based magnetic compounds were synthesized by anchoring N-oxide type TEMPO radicals onto an Anderson type polyoxometalate cluster. The complexes were structurally characterised by single crystal X-ray diffraction and the intramolecular paramagnetic interactions between TEMPO radicals and Mn ions of the resulting hybrids were investigated in detail by electron paramagnetic resonance and the Evans NMR method.

引用

页码：2350 / 2353

页数：4

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