Effect of sodium lauryl sulphate (SLS) on nickel electrowinning from acidic sulphate solutions

被引：26

作者：

Mohanty, U. S. ^{[1
]}

Tripathy, B. C. ^{[2
]}

Das, S. C. ^{[2
]}

Singh, P. ^{[1
]}

Misra, V. N. ^{[3
]}

机构：

[1] Murdoch Univ, Dept Chem, Murdoch, WA 6150, Australia

[2] Inst Minerals & Mat Technol, Bhubaneswar 13, Orissa, India

[3] Dept Ind & Resources, Perth, WA 6004, Australia

来源：

HYDROMETALLURGY | 2009年 / 100卷 / 1-2期

关键词：

Nickel electrowinning; Sodium lauryl sulphate; Electrochemical studies; Current efficiency; Cathode morphology; Crystal orientation; ELECTRODEPOSITION; PARAMETERS; MORPHOLOGY;

D O I：

10.1016/j.hydromet.2009.10.003

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The effect of sodium lauryl sulphate (SLS) on the cathodic current efficiency (CE), surface morphology, crystallographic orientations and polarization behaviour of the stainless steel cathode during nickel electrowinning from acidic sulphate solutions was investigated. The results indicated that SLS did not have a significant effect on the cathodic current efficiency. However, noticeable changes in the surface morphology and deposit quality were observed. Cyclic and linear sweep voltammetric studies revealed that an increase in SLS concentration from 2 to 40 mg dm(-3) increased the cathodic potential and shifted the nucleation overpotential (NOP) towards more negative values which was also reflected in the decrease in the rate of electron transfer i.e. i(0) values obtained on both the stainless steel and nickel substrates. The presence of SLS did not change the fcc structure of the electrodeposited nickel but affected the peak intensities of the various crystal planes. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：60 / 64

页数：5

共 15 条

[1] ELECTROCHEMICAL NUCLEATION OF NICKEL ON VITREOUS CARBON ELECTRODES - THE INFLUENCE OF ORGANIC ADDITIVES [J].

ALBALAT, R ;

GOMEZ, E ;

MULLER, C ;

SARRET, M ;

VALLES, E .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1991, 21 (08) :709-715

[2]

Borikar DK, 2006, METALURGIJA, V45, P3

[3] The influence of electrolysis parameters on the composition and morphology of Co-Ni alloys [J].

Burzynska, L ;

Rudnik, E .

HYDROMETALLURGY, 2000, 54 (2-3) :133-149

[4] INFLUENCE OF UNSATURATED ORGANIC-MOLECULES IN ELECTROCRYSTALLIZATION OF NICKEL [J].

COSTAVARAS, TA ;

FROMENT, M ;

GOFF, AHL ;

GEORGOUL.C .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1973, 120 (07) :867-874

[5] SIMULTANEOUS ELECTRODEPOSITION OF NICKEL AND HYDROGEN ON A ROTATING DISK ELECTRODE [J].

DORSCH, RK .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1969, 21 (03) :495-&

[6]

GARY AG, 1953, MODERN ELECTROPLATIN, P313

[7] BORIC-ACID AS A CATALYST IN NICKEL PLATING SOLUTIONS [J].

HOARE, JP .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (12) :3102-3103

[8] ROLE OF BUFFERS AND ANIONS IN NIFE ELECTRODEPOSITION [J].

HORKANS, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (11) :1861-1867

[9] EFFECT OF SURFACTANTS ON RECOVERY OF NICKEL FROM NICKEL-PLATING WASTE-WATER BY ELECTROWINNING [J].

HUANG, CH .

WATER RESEARCH, 1995, 29 (08) :1821-1826

[10]

Lowenheim F.A., 1974, Modern Electroplating

← 1 2 →