Synthesis, characterization and crystal structure of an unsymmetric Samarium(III) cryptate

被引：1

作者：

Chen, QY

Luo, QH ^{[1
]}

Mei, YH

Liu, YJ

Zhou, ZY

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610015, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2000年 / 51卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Samarium(III); cryptate; crystal structure; macrocyclic ligand;

D O I：

10.1080/00958970008055124

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Sm(H3L)(NO3)(H2O)](NO3)(2) . H2O was synthesized by the (2+3) condensation of tris(2-aminoethyl)amine with 2,6-diformyl-4-chlorophenol in the presence of Sm3+. Its crystal structure has been determined. In the complex the coordination number of Sm3+ is nine. A water molecule is encapsulated in the cryptate as a guest, confirmed by electrospray mass spectrometry, thermal analysis and the X-ray crystal structure.

引用

收藏

页码：125 / 134

页数：10

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