Three-dimensional Nickel(II) Heptacyanomolybdate(III)-based Magnet

被引：14
|
作者：
Tomono, Keisuke [1 ]
Tsunobuchi, Yoshihide [1 ]
Nakabayashi, Koji [1 ]
Kosaka, Wataru [1 ]
Matsuda, Tomoyuki [1 ]
Ohkoshi, Shin-ichi [1 ]
机构：
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
来源：
CHEMISTRY LETTERS | 2009年 / 38卷 / 08期
关键词：
RUBIDIUM MANGANESE HEXACYANOFERRATE; PRUSSIAN BLUE ANALOGS; ORDERING TEMPERATURE; PHASE-TRANSITION; SPIN-CROSSOVER; DEGREES-C; HEXACYANOCHROMATE; CYANOMOLYBDATES; MAGNETIZATION;
D O I：
10.1246/cl.2009.810
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein we prepared a three-dimensional nickel heptacyanomolybdate-based magnet, K0.6Ni1.7II[Mo-III(CN)(7)]center dot 5.5H(2)O center dot 0.5CH(3)OH. This compound exhibited magnetic ordering with a Curie temperature of 28K due to ferromagnetic coupling between magnetic spins on Ni-II (S = 1) and Mo-III (S = 1/2).
引用
收藏
页码：810 / 811
页数：2
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