From pink to blue and back to pink again: changing the Co(II) ligation in a two-dimensional coordination network upon desolvation

被引：15

作者：

Chisca, Diana ^{[1
]}

Croitor, Lilia ^{[1
]}

Coropceanu, Eduard B. ^{[2
]}

Petuhov, Oleg ^{[2
]}

Baca, Svetlana G. ^{[1
]}

Kraemer, Karl ^{[3
]}

Liu, Shi-Xia ^{[3
]}

Decurtins, Silvio ^{[3
]}

Rivera-Jacquez, Hector J. ^{[4
,5
]}

Masunov, Artem E. ^{[4
,5
,6
]}

Fonari, Marina S. ^{[1
]}

机构：

[1] Acad Sci R Moldova, Inst Appl Phys, MD-2028 Kishinev, Moldova

[2] Acad Sci R Moldova, Inst Chem, MD-2028 Kishinev, Moldova

[3] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

[4] Univ Cent Florida, NanoSci Technol Ctr, Dept Chem, Dept Phys, Orlando, FL 32826 USA

[5] Univ Cent Florida, Florida Solar Energy Ctr, Orlando, FL 32826 USA

[6] Natl Res Nucl Univ MEPhI, Dept Condensed Matter Phys, Moscow 115409, Russia

来源：

CRYSTENGCOMM | 2016年 / 18卷 / 03期

基金：

俄罗斯科学基金会; 瑞士国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; SINGLE-CRYSTAL; SUPRAMOLECULAR ISOMERISM; POLYMERIC ZN(II); CD(II) SULFATES; DESIGN; TRANSFORMATION; COMPLEXES; CHEMISTRY; MAGNETISM;

D O I：

10.1039/c5ce01581b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heating of a pink two-dimensional Co(II) coordination network {[Co-2(mu(2)-OH2)(bdc)(2)(S-nia)(2)(H2O)(dmf)]center dot 2(dmf)center dot(H2O)}(n) (1) built from 1,4-benzenedicarboxylic acid (H(2)bdc) residues and thionicotinamide (S-nia) ligands initiates a single-crystal-to-single-crystal transition accompanied by removal of both coordinated and co-crystallized solvents. In the dry blue form, [Co(bdc)(S-nia)](n) (dry_1), the Co(II) centers changed from an octahedral to a square pyramidal configuration.

引用

页码：384 / 389

页数：6

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