Nanostructured Coatings for Stone Protection: An Overview

被引:45
作者
Ruffolo, Silvestro Antonio [1 ]
La Russa, Mauro Francesco [1 ]
机构
[1] Univ Calabria, Dipartimento Biol Ecol & Sci Terra, Arcavacata Di Rende, Italy
关键词
stone protection; nanostructured coatings; nanoparticles; cultural heritage conservation; superhydrophobic coatings; photocatalytic coatings; WATER-REPELLENT; PHOTOCATALYTIC ACTIVITY; SILICA NANOPARTICLES; BUILDING-MATERIALS; TITANIUM-DIOXIDE; TIO2; COATINGS; BLACK CRUSTS; DETERIORATION; SURFACES; MARBLE;
D O I
10.3389/fmats.2019.00147
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The protection of the stone materials represents an ongoing challenge in the field of conservation of cultural heritage. Protective coatings are used to make the stone more resistant against pollutants, biological growths, and especially against the action of water. In last decades, nanoparticles were synthetized and tested to improve the performance of such coatings. In this review, two main enhanced coatings are reported: superhydrophobic coatings and photocatalytic coatings. The first ones have a very low adhesion, so dirty, pollutants and colonies of microorganisms can be easily "washed out" by the water. Photocatalytic coatings are able to oxidize organic matter on their surface, thanks to the combination of light and photocatalyst. The state-of-art of both technologies are discussed with advantages and drawbacks.
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页数:8
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共 93 条
  • [1] Using ZnO nanoparticles in fungal inhibition and self-protection of exposed marble columns in historic sites
    Aldosari, Mohammad Ateeq
    Darwish, Sawsan S.
    Adam, Mahmoud A.
    Elmarzugi, Nagib A.
    Ahmed, Sayed M.
    [J]. ARCHAEOLOGICAL AND ANTHROPOLOGICAL SCIENCES, 2019, 11 (07) : 3407 - 3422
  • [2] Synthesis and characterization of photocatalytic hydrophobic hybrid TiO2-SiO2 coatings for building applications
    Alfieri, Ilaria
    Lorenzi, Andrea
    Ranzenigo, Luca
    Lazzarini, Laura
    Predieri, Giovanni
    Lottici, Pier Paolo
    [J]. BUILDING AND ENVIRONMENT, 2017, 111 : 72 - 79
  • [3] Diagnostic analysis of stone materials from underwater excavations: the case study of the Roman archaeological site of Baia (Naples, Italy)
    Aloise, P.
    Ricca, M.
    La Russa, M. F.
    Ruffolo, S. A.
    Belfiore, C. M.
    Padeletti, G.
    Crisci, G. M.
    [J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2014, 114 (03): : 655 - 662
  • [4] [Anonymous], 1993, P ICOM COMMITEE CONS
  • [5] Light-induced charge separation across Ru(II)-modified nanocrystalline TiO2 interfaces with phenothiazine donors
    Argazzi, R
    Bignozzi, CA
    Heimer, TA
    Castellano, FN
    Meyer, GJ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14) : 2591 - 2597
  • [6] Waterborne Superhydrophobic and Superoleophobic Coatings for the Protection of Marble and Sandstone
    Aslanidou, Dimitra
    Karapanagiotis, Ioannis
    Lampakis, Dimitrios
    [J]. MATERIALS, 2018, 11 (04):
  • [7] Soft and hard nanomaterials for restoration and conservation of cultural heritage
    Baglioni, P
    Giorgi, R
    [J]. SOFT MATTER, 2006, 2 (04) : 293 - 303
  • [8] Self-cleaning applications of TiO2 by photo-induced hydrophilicity and photocatalysis
    Banerjee, Swagata
    Dionysiou, Dionysios D.
    Pillai, Suresh C.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 176 : 396 - 428
  • [9] Impact of air pollution in deterioration of carbonate building materials in Italian urban environments
    Barca, Donatella
    Comite, Valeria
    Belfiore, Cristina M.
    Bonazza, Alessandra
    La Russa, Mauro F.
    Ruffolo, Silvestro A.
    Crisci, Gino M.
    Pezzino, Antonino
    Sabbioni, Cristina
    [J]. APPLIED GEOCHEMISTRY, 2014, 48 : 122 - 131
  • [10] Enhanced self-cleaning properties of N-doped TiO2 coating for Cultural Heritage
    Bergamonti, L.
    Predieri, G.
    Paz, Y.
    Fornasini, L.
    Lottici, P. P.
    Bondioli, F.
    [J]. MICROCHEMICAL JOURNAL, 2017, 133 : 1 - 12