Weighted density Lattice Boltzmann approach to fluids under confinement

被引:3
作者
Marconi, Umberto Marini Bettolo [1 ]
Melchionna, Simone [2 ]
机构
[1] Univ Camerino, Scuola Sci & Tecnol, Ist Nazl Fis Nucl, Sez Perugia, I-62032 Camerino, Italy
[2] Univ Roma La Sapienza, Dipartimento Fis, Consiglio Nazl Ric, CNR IPCF, I-00185 Rome, Italy
关键词
nanofluidics; Lattice Boltzmann method; density functional theory; weighted density approximation; viscosity; FUNCTIONAL THEORY; TRANSPORT; EQUATION; FLOWS; MODEL;
D O I
10.1080/00268976.2013.771801
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Enskog-like kinetic approach, recently introduced by us to study strongly inhomogeneous fluids, is reconsidered in order to improve the description of the transport coefficients. The approach is based on a separation of the interaction between hydrodynamic and non-hydrodynamic parts. The latter is treated within a simple relaxation approximation. We show that, by considering the non-hydrodynamic part via a weighted density approximation, we obtain a better prediction of the transport coefficients. By virtue of the simplicity of the kinetic equation we are able to solve numerically the phase space distribution in the presence of inhomogeneities, such as confining surfaces, via a Lattice Boltzmann method. Analytical estimates of the importance of these corrections to the transport coefficients in bulk conditions is provided. Poiseuille flow of the hard-sphere fluid confined between two parallel smooth walls is studied and their pore-averaged properties are determined.
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页码:3126 / 3135
页数:10
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