Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)]2[Cr(CN)6]•H2O

被引：0
|
作者：
Miyasaka, H [1 ]
Okawa, H
Matsumoto, N
机构：
[1] Kyoto Univ, Fac Engn, Dept Synth Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan
[2] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 812, Japan
[3] Kumamoto Univ, Fac Sci, Dept Chem, Kumamoto 860, Japan
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1999年 / 335卷
关键词：
ferrimagnet; two-dimensional layered compound; manganese(III) salen analogous; hexacyanochromate(III);
D O I：
暂无
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A series of bimetallic compounds of the general formula K[Mn(3-MeOsalen)](2)[M(CN)(6)] (M = Co3+, Fe3+, Mn3+, Cr3+) has a similar 2-D network structure but their magnetic properties vary depending upon the nature of the metal ion of [M(CN)(6)](3-) and the interlayer magnetic interaction. The magnetic property of K[Mn(3-MeOsalen)](2)[Cr(CN)(6)]. H2O shows a ferrimagnetic nature arising from an intralayer ferrimagnetic ordering due to the antiferromagnetic spin arrangement of neighboring high spin Mn3+ and Cr3+, and an interlayer ferromagnetic interaction.
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收藏
页码：1015 / 1023
页数：9
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