Synthesis and Characterization of a 2,6-Diiminophenylgermanium(II) Hydroxide, Azide, and Triazaphospole

被引：9
作者：
Chia, Siew-Peng [1 ]
Li, Yongxin [1 ]
So, Cheuk-Wai [1 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 18期
关键词：
N-HETEROCYCLIC GERMYLENES; PHOSPHORUS-COMPOUNDS; DIVALENT GERMANIUM; CLICK CHEMISTRY; REACTIVITY; DERIVATIVES; ANALOGS; COMPOUND; BOND;
D O I：
10.1021/om400411s
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the 2,6-diiminophenylgermanium(II) chloride [LGeCl] (1; L = 2,6-(HC=NAr)(2)C6H3, Ar = 2,6-(Pr2C6H3)-C-i) with Me3SnOH and NaN3 in THF afforded {LGeOH(SnMe3Cl)} (2) and [LGeN3] (3), respectively. Compound 3 underwent an uncatalyzed 1,3-dipolar cycloaddition reaction with 1-adamantylphosphaalkyne to afford the 2,6-diiminophenylgermanium(II) triazaphosphole [LGe{N3C(Ad)P}] (4).
引用
收藏
页码：5231 / 5234
页数：4
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