Synthesis and Characterization of a 2,6-Diiminophenylgermanium(II) Hydroxide, Azide, and Triazaphospole

被引：9
|
作者：
Chia, Siew-Peng [1 ]
Li, Yongxin [1 ]
So, Cheuk-Wai [1 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 18期
关键词：
N-HETEROCYCLIC GERMYLENES; PHOSPHORUS-COMPOUNDS; DIVALENT GERMANIUM; CLICK CHEMISTRY; REACTIVITY; DERIVATIVES; ANALOGS; COMPOUND; BOND;
D O I：
10.1021/om400411s
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the 2,6-diiminophenylgermanium(II) chloride [LGeCl] (1; L = 2,6-(HC=NAr)(2)C6H3, Ar = 2,6-(Pr2C6H3)-C-i) with Me3SnOH and NaN3 in THF afforded {LGeOH(SnMe3Cl)} (2) and [LGeN3] (3), respectively. Compound 3 underwent an uncatalyzed 1,3-dipolar cycloaddition reaction with 1-adamantylphosphaalkyne to afford the 2,6-diiminophenylgermanium(II) triazaphosphole [LGe{N3C(Ad)P}] (4).
引用
收藏
页码：5231 / 5234
页数：4
相关论文
共 50 条
  • [21] Synthesis, magnetic behavior and structural characterization of novel one-dimensional copper(II) coordination polymer based on azide and oxalate bridges
    Switlicka-Olszewska, A.
    Machura, B.
    Mrozinski, J.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 43 : 86 - 89
  • [22] Tridentate complexes of 2,6-bis(4-substituted-1,2,3-triazol-1-ylmethyl)pyridine and its organic azide precursors: an application of the copper(II) acetate-accelerated azide-alkyne cycloaddition
    Brotherton, Wendy S.
    Guha, Pampa M.
    Phan, Hoa
    Clark, Ronald J.
    Shatruk, Michael
    Zhu, Lei
    DALTON TRANSACTIONS, 2011, 40 (14) : 3655 - 3665
  • [23] Synthesis and characterization of group 5 imido complexes supported by the 2,6-dichloroaryl β-diketiminato ligand
    Nechayev, Michael
    Kriegel, Benjamin M.
    Gianetti, Thomas L.
    Bergman, Robert G.
    Arnold, John
    INORGANICA CHIMICA ACTA, 2014, 422 : 114 - 119
  • [24] Synthesis and structural characterization of π-allylpalladium(II) complexes with bis(imidazol-2-ylidene)borate ligands
    Liu, Yuan-Zhong
    Wang, Jing
    Wang, Gao-Feng
    Chen, Lei
    Chen, Xue-Tai
    Xue, Zi-Ling
    POLYHEDRON, 2014, 83 : 44 - 49
  • [25] Synthesis, Characterization, and Antibacterial Studies of New Cu(II) and Pd(II) Complexes with 6-Methyl-2-Thiouracil and 6-Propyl-2-Thiouracil
    Marinova, Petya
    Hristov, Mariyan
    Tsoneva, Slava
    Burdzhiev, Nikola
    Blazheva, Denica
    Slavchev, Aleksandar
    Varbanova, Evelina
    Penchev, Plamen
    APPLIED SCIENCES-BASEL, 2023, 13 (24):
  • [26] Nickel(II) and copper(II) complexes of 2-(2-pyridyl)benzimidazole: synthesis and structural characterization
    Altaf, Muhammad
    Stoeckli-Evans, Helen
    TRANSITION METAL CHEMISTRY, 2009, 34 (06) : 613 - 620
  • [27] Synthesis and characterization of a proton transfer salt between 2,6-pyridinedicarboxylic acid and 2-aminobenzothiazole, and its complexes and their inhibition studies on carbonic anhydrase isoenzymes
    Ilkimen, Halil
    Yenikaya, Cengiz
    Sari, Musa
    Bulbul, Metin
    Tunca, Ekrem
    Dal, Hakan
    JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY, 2014, 29 (03) : 353 - 361
  • [28] A mixed phenoxo and end-on azide bridged dinuclear copper(II) Schiff base complex: synthesis, structure, magnetic characterization and DFT study
    Khan, Samim
    Herrero, Santiago
    Gonzalez-Prieto, Rodrigo
    Drew, Michael. G. B.
    Banerjee, Snehasis
    Chattopadhyay, Shouvik
    NEW JOURNAL OF CHEMISTRY, 2018, 42 (16) : 13512 - 13519
  • [29] Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II)
    Sahebalzamani, Hajar
    Ghammamy, Shahriare
    Dexhkam, Shaghayegh
    Moghadam, Alireza Hemati
    Siavoshifar, Farhod
    E-JOURNAL OF CHEMISTRY, 2011, 8 : S13 - S18
  • [30] Heterolysis of H2 Across a Classical Lewis Pair, 2,6-LutidineBCl3: Synthesis, Characterization, and Mechanism
    Ginovska, Bojana
    Autrey, Tom
    Parab, Kshitij
    Bowden, Mark E.
    Potter, Robert G.
    Camaioni, Donald M.
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (44) : 15713 - 15719
12345