Redox-Responsive Self-Healing for Corrosion Protection

被引：202
作者：
Vimalanandan, Ashokanand [1 ]
Lv, Li-Ping [2 ]
The Hai Tran [1 ]
Landfester, Katharina [2 ]
Crespy, Daniel [2 ]
Rohwerder, Michael [1 ]
机构：
[1] Max Planck Inst Eisenforsch GmbH, D-40237 Dusseldorf, Germany
[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
来源：
ADVANCED MATERIALS | 2013年 / 25卷 / 48期
关键词：
conducting polymers; galvanized steel; redox responses; scanning kelvin probe; self-healing materials; CONDUCTING POLYMERS; ELECTROLYTE LAYERS; PART; NANOCONTAINERS; DELAMINATION; COATINGS; ZINC; INHIBITION; RELEASE; METALS;
D O I：
10.1002/adma.201302989
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Raspberry-shaped redox-responsive capsules for storing corrosion inhibitors are introduced, targeted to solve the drawbacks of conducting-polymer-based coating systems for corrosion protection. These capsules synthesized via the miniemulsion technique have a remarkable release property upon reduction (onset of corrosion) and cease release upon reoxidation (passivation of the defect). The self-healing capability is demonstrated by application of these capsules as part of a composite coating on zinc. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6980 / 6984
页数：5
相关论文
共 33 条
[1]   Conducting-polymer nanotubes for controlled drug release [J].
Abidian, MR ;
Kim, DH ;
Martin, DC .
ADVANCED MATERIALS, 2006, 18 (04) :405-+
[2]   Corrosion protection by polyaniline-coated latex microspheres [J].
Abu, YM ;
Aoki, K .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 583 (01) :133-139
[3]   Conducting polymers as a basis for responsive materials systems [J].
Barisci, JN ;
Lewis, TW ;
Spinks, GM ;
Too, CO ;
Wallace, GG .
JOURNAL OF INTELLIGENT MATERIAL SYSTEMS AND STRUCTURES, 1998, 9 (09) :723-731
[4]   Polydimethylsiloxane-based self-healing materials [J].
Cho, SH ;
Andersson, HM ;
White, SR ;
Sottos, NR ;
Braun, PV .
ADVANCED MATERIALS, 2006, 18 (08) :997-+
[5]   Self-Healing Polymer Coatings [J].
Cho, Soo Hyoun ;
White, Scott R. ;
Braun, Paul V. .
ADVANCED MATERIALS, 2009, 21 (06) :645-+
[6]   Miniemulsion polymerization as a versatile tool for the synthesis of functionalized polymers [J].
Crespy, Daniel ;
Landfester, Katharina .
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2010, 6 :1132-1148
[7]   Copolymers Structures Tailored for the Preparation of Nanocapsules [J].
Fickert, Johannes ;
Wohnhaas, Christian ;
Turshatov, Andrey ;
Landfester, Katharina ;
Crespy, Daniel .
MACROMOLECULES, 2013, 46 (03) :573-579
[8]   Efficient Encapsulation of Self-Healing Agents in Polymer Nanocontainers Functionalized by Orthogonal Reactions [J].
Fickert, Johannes ;
Makowski, Marcin ;
Kappl, Michael ;
Landfester, Katharina ;
Crespy, Daniel .
MACROMOLECULES, 2012, 45 (16) :6324-6332
[9]   Potential control under thin aqueous layers using a Kelvin Probe [J].
Frankel, G. S. ;
Stratmann, M. ;
Rohwerder, M. ;
Michalik, A. ;
Maier, B. ;
Dora, J. ;
Wicinski, M. .
CORROSION SCIENCE, 2007, 49 (04) :2021-2036
[10]   The delamination of polymeric coatings from electrogalvanised steel -: a mechanistic approach.: Part 1:: delamination from a defect with intact zinc layer [J].
Fürbeth, W ;
Stratmann, M .
CORROSION SCIENCE, 2001, 43 (02) :207-227
1234