The pseudo-racemic complex bis[tris(2,2'-bipyridine)ruthenium(II)] hexacyanocobaltate(III) chloride octahydrate, [Ru(bpy)(3)](2)[Co(CN)(6)]Cl.8H(2)O

被引：15
作者：
Tamura, H [1 ]
Ikeda, N [1 ]
Iguro, T [1 ]
Ohno, T [1 ]
Matsubayashi, G [1 ]
机构：
[1] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷
关键词：
D O I：
10.1107/S0108270196000042
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystals of [Ru(C10H8N2)(3)](2)[Co(CN)(6)]Cl.8H(2)O (C10H8N2 = bpy = 2,2'-bipyridine) which belong to the space group C2 are characterized by two 'pseudo-racemic' crystallographically independent [Ru(bpy)(3)](2+) cations. Three kinds of layers are found in the crystal structure: (i) a layer consisting of Lambda-[Ru(bpy)(3)](2+) cations and water molecules; (ii) a layer of [Co(CN)(6)](3-) and Cl- anions and water molecules; (iii) a layer of Delta-[Ru(bpy)(3)](2+) cations and water molecules. The layers are stacked in the order (i), (ii), (iii) and (ii) almost perpendicularly to the c axis. Some O ... O, O ... N(cyano) and O ... Cl hydrogen bonds construct networks within and between the layers.
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页码：1394 / 1399
页数：6
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