Efficient sulfur-tolerant bimetallic catalysts for hydrogen generation from diesel fuel

被引：22

作者：

Cheekatamarla, PK ^{[1
]}

Lane, AM ^{[1
]}

机构：

[1] Univ Alabama, Dept Chem Engn, Tuscaloosa, AL 35487 USA

来源：

JOURNAL OF POWER SOURCES | 2006年 / 153卷 / 01期

关键词：

hydrogen; fuel cells; autothermal; reforming; diesel; sulfur;

D O I：

10.1016/j.jpowsour.2005.03.176

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic autothermal reforming (ATR) of synthetic diesel and JP8 over supported metal catalysts has been investigated in the present study. Bimetallic catalysts exhibited superior performance compared to the commercial catalyst and the monometallic counterparts. BET, temperature-programmed desorption (TPD), temperature-programmed reduction (TPR) and XPS were utilized for characterizing these formulations, which showed that the enhanced stability is due to a strong metal-metal and metal-support interaction in the catalyst. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：157 / 164

页数：8

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