Synthesis, crystal structures, and biological activity of zinc(II) complexes derived from 4-bromo-2-[(3-diethylaminopropylimino)methyl]phenol

被引：7

作者：

Shi, D. H. ^{[1
,2
]}

Cao, Z. L. ^{[1
]}

Liu, W. W. ^{[1
]}

Xu, R. B. ^{[1
]}

Gao, L. L. ^{[1
]}

Zhang, Q. ^{[1
]}

You, Z. ^{[3
]}

机构：

[1] Huaihai Inst Technol, Sch Chem Engn, Lianyungang 222005, Peoples R China

[2] Huaihai Inst Technol, JiangSu Key Lab Marine Biotechnol, Lianyungang 222005, Peoples R China

[3] Liaoning Normal Univ, Dept Chem, Dalian 116029, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 39卷 / 03期

关键词：

UREASE INHIBITORY-ACTIVITIES; SCHIFF-BASE LIGAND; METAL-COMPLEXES;

D O I：

10.1134/S1070328413030111

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Schiff base zinc(II) complexes, [ZnBr2L] (I) and [ZnCl2L] (II), where L is 4-bromo-2-[(3-diethylaminopropylimino)methyl]phenol, were synthesized and characterized by physico-chemical methods and single crystal X-ray diffraction. The crystal of I is monoclinic: space group P2(1)/n a = 7.250 (2), b = 16.136 (3), c = 15.802 (3) , beta = 90.027 (3)A degrees, V = 1848.6 (7) (3), Z = 4. The crystal of II is monoclinic: space group P2(1)/n, a = 7.177 (3), b = 15.970 (4), c = 15.689 (3), beta = 91.674 (3)A degrees, V = 1797.5 (9) (3), Z = 4. The Zn atom in each complex is four-coordinated by one phenolate O and one imine N atoms of the Schiff base ligand and two halide atoms, forming a tetrahedral coordination. The urease inhibitory activities of the complexes were evaluated.

引用

页码：297 / 300

页数：4

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