Mineralization routes to polyphosphides:: Cu2P20 and Cu5InP16

被引：44

作者：

Lange, Stefan ^{[1
]}

Bawohl, Melanie ^{[1
]}

Weihrich, Richard ^{[2
]}

Nilges, Tom ^{[1
]}

机构：

[1] Inst Anorgan & Analyt Chem, D-48149 Munster, Germany

[2] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 30期

关键词：

coinage metals; indium; mineralization reactions; phosphorus; polyphosphides;

D O I：

10.1002/anie.200705540

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Mineralization chemistry: Cu2P20 and Cu5InP16 were synthesized by a mineralization reaction from the elements and binary starting materials. Cu2P20 is the first representative retaining the structural features of violet or fibrous phosphorus in a binary compound (see picture). Cu5InP 16 displays a previously unseen layered polyphosphide substructure built up of six-membered rings connected via four phosphorus bridges. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5654 / 5657

页数：4

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