Ni/Pd@MIL-101: Synergistic Catalysis with Cavity-Conform Ni/Pd Nanoparticles

被引：166
作者：
Hermannsdoerfer, Justus [1 ]
Friedrich, Martin [1 ]
Miyajima, Nobuyoshi [2 ]
Albuquerque, Rodrigo Q. [3 ]
Kuemmel, Stephan
Kempe, Rhett [1 ]
机构：
[1] Univ Bayreuth, Lehrstuhl Anorgan Chem 2, D-95440 Bayreuth, Germany
[2] Univ Bayreuth, Bayer Geoinst, D-95440 Bayreuth, Germany
[3] Univ Sao Paulo, Inst Chem Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 46期
关键词：
bimetallic catalysis; metal-organic frameworks; nickel; palladium; porous coordination polymers; METAL-ORGANIC FRAMEWORK; ORGANOMETALLIC CVD-PRECURSORS; POROUS COORDINATION POLYMERS; INCLUSION-COMPOUNDS; AEROBIC OXIDATION; HYDROGEN STORAGE; PD NANOPARTICLES; GOLD CLUSTERS; MOF-5; INFILTRATION;
D O I：
10.1002/anie.201205078
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A perfect fit: Cavity-conform bimetallic Ni/Pd nanoparticles of different composition were generated in the metal-organic framework MIL-101. Experimental evidence and molecular dynamic simulations indicate the existence of mixed bimetallic particles. Pronounced synergistic effects have been observed in liquid-phase catalysis. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11473 / 11477
页数：5
相关论文
共 53 条
[1]   ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].
ABRAHAMS, BF ;
HOSKINS, BF ;
MICHAIL, DM ;
ROBSON, R .
NATURE, 1994, 369 (6483) :727-729
[2]  
[Anonymous], 1958, Constitution of Binary Alloys
[3]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[4]   Catalysis by metal nanoparticles embedded on metal-organic frameworks [J].
Dhakshinamoorthy, Amarajothi ;
Garcia, Hermenegildo .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (15) :5262-5284
[5]   Metallic and bimetallic nanocatalysts incorporated into highly porous coordination polymer MIL-101 [J].
El-Shall, M. Samy ;
Abdelsayed, Victor ;
Khder, Abd El Rahman S. ;
Hassan, Hassan M. A. ;
El-Kaderi, Hani M. ;
Reich, Thomas E. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (41) :7625-7631
[6]   ZnO@ZIF-8: stabilization of quantum confined ZnO nanoparticles by a zinc methylimidazolate framework and their surface structural characterization probed by CO2 adsorption [J].
Esken, Daniel ;
Noei, Heshmat ;
Wang, Yuemin ;
Wiktor, Christian ;
Turner, Stuart ;
Van Tendeloo, Gustaaf ;
Fischer, Roland A. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (16) :5907-5915
[7]   Au@ZIFs: Stabilization and Encapsulation of Cavity-Size Matching Gold Clusters inside Functionalized Zeolite Imidazolate Frameworks, ZIFs [J].
Esken, Daniel ;
Turner, Stuart ;
Lebedev, Oleg I. ;
Van Tendeloo, Gustaaf ;
Fischer, Roland A. .
CHEMISTRY OF MATERIALS, 2010, 22 (23) :6393-6401
[8]   Pd@MOF-5: limitations of gas-phase infiltration and solution impregnation of [Zn4O(bdc)3] (MOF-5) with metal-organic palladium precursors for loading with Pd nanoparticles [J].
Esken, Daniel ;
Zhang, Xiaoning ;
Lebedev, Oleg I. ;
Schroeder, Felicitas ;
Fischer, Roland A. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (09) :1314-1319
[9]   A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F ;
Dutour, J ;
Surblé, S ;
Margiolaki, I .
SCIENCE, 2005, 309 (5743) :2040-2042
[10]   Nanoalloys: From theory to applications of alloy clusters and nanoparticles [J].
Ferrando, Riccardo ;
Jellinek, Julius ;
Johnston, Roy L. .
CHEMICAL REVIEWS, 2008, 108 (03) :845-910
123456