Ni/Pd@MIL-101: Synergistic Catalysis with Cavity-Conform Ni/Pd Nanoparticles

被引：166
作者：
Hermannsdoerfer, Justus [1 ]
Friedrich, Martin [1 ]
Miyajima, Nobuyoshi [2 ]
Albuquerque, Rodrigo Q. [3 ]
Kuemmel, Stephan
Kempe, Rhett [1 ]
机构：
[1] Univ Bayreuth, Lehrstuhl Anorgan Chem 2, D-95440 Bayreuth, Germany
[2] Univ Bayreuth, Bayer Geoinst, D-95440 Bayreuth, Germany
[3] Univ Sao Paulo, Inst Chem Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 46期
关键词：
bimetallic catalysis; metal-organic frameworks; nickel; palladium; porous coordination polymers; METAL-ORGANIC FRAMEWORK; ORGANOMETALLIC CVD-PRECURSORS; POROUS COORDINATION POLYMERS; INCLUSION-COMPOUNDS; AEROBIC OXIDATION; HYDROGEN STORAGE; PD NANOPARTICLES; GOLD CLUSTERS; MOF-5; INFILTRATION;
D O I：
10.1002/anie.201205078
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A perfect fit: Cavity-conform bimetallic Ni/Pd nanoparticles of different composition were generated in the metal-organic framework MIL-101. Experimental evidence and molecular dynamic simulations indicate the existence of mixed bimetallic particles. Pronounced synergistic effects have been observed in liquid-phase catalysis. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11473 / 11477
页数：5
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